4.6 Article

Sodium doping in ZnO crystals

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APPLIED PHYSICS LETTERS
卷 106, 期 2, 页码 -

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AMER INST PHYSICS
DOI: 10.1063/1.4905594

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  1. Center for Materials Research at Washington State University

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ZnO bulk single crystals were doped with sodium by thermal diffusion. Positron annihilations spectroscopy confirms the filling of zinc vacancies, to >6 mu m deep in the bulk. Secondary-ion mass spectrometry measurement shows the diffusion of sodium up to 8 mu m with concentration (1-3.5) x 10(17) cm(-3). Broad photoluminescence excitation peak at 3.1 eV, with onset appearance at 3.15 eV in Na:ZnO, is attributed to an electronic transition from a Na-Zn level at similar to(220-270) meV to the conduction band. Resistivity in Na doped ZnO crystals increases up to (4-5) orders of magnitude at room temperature. (C) 2015 AIP Publishing LLC.

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