期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 11, 页码 4121-4124出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja500661k
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资金
- EU
- EPSRC
- NSERC Canada
- Engineering and Physical Sciences Research Council [EP/K017799/1] Funding Source: researchfish
- EPSRC [EP/K017799/1] Funding Source: UKRI
Monodisperse fiber-like micelles with a crystalline pi-conjugated polythiophene core with lengths up to ca. 700 nm were successfully prepared from the diblock copolymer poly(3-hexylthiophene)-block-poly-styrene using a one-dimensional self-seeding technique. Addition of a polythiophene block copolymer with a different corona-forming block to the resulting nanofibers led to the formation of segmented B-A-B triblock co-micelles by crystallization-driven seeded growth. The key to these advances appears to be the formation of a relatively defect-free crystalline micelle core under the self-seeding conditions.
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