期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 19, 页码 6888-6891出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5029809
关键词
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资金
- National Institutes of Health (NIH) [2R01GM068433]
- Alexander von Humboldt Foundation
The first catalytic, highly C3-selective, stereosepecific ring-opening reaction of 2,3-epoxy alcohols and 2,3-epoxy sulfonamides has been accomplished. This process was efficiently promoted by W-salts, and the developed method was applicable to various epoxides with diverse N- and O-nucleophiles affording the products in good to excellent yields (up to 95%) and generally with high regioselectivities (C3:C2 up to >99:1).
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