期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 37, 页码 13636-13639出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4068172
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [21106005, 25105729, 21106001] Funding Source: KAKEN
We have developed a nickel-catalyzed transformation, in which phthalimides react with trimethylsilyl-substituted alkynes in the presence of Ni(0)/PMe3/MAD catalyst to provide isoindolinones. The reaction process displays an unusual mechanistic feature-decarbonylation and alkylidenation. The use of both trimethylsilyl-substiuted alkynes and MAD was found to be essential for the transformation with high selectivities.
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