期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 32, 页码 11712-11715出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja405043g
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资金
- National Science Foundation [CHE 1213246]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1213246] Funding Source: National Science Foundation
A highly effective synthesis of 2,3-fused pyrroles from cyclic ketones has been achieved. The transformation includes a rhodium-catalyzed reaction of 4-alkenyl-1-sulfonyl-1,2,3-triazoles featuring an unusual 4 pi electrocyclization. The methodology was further extended to the synthesis of indoles using a one-pot reaction starting from 1-ethynylcyclohexenes.
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