期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 18, 页码 6747-6749出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja402893z
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资金
- NIH [GM-43214]
Catalysis of Cope-type rearrangements of bis-homoallylic hydroxylamines is demonstrated using chiral thiourea derivatives. This formal intramolecular hydroamination reaction provides access to highly enantioenriched alpha-substituted pyrrolidine products and represents a complementary approach to metal-catalyzed methods.
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