期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 38, 页码 15704-15707出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja3075314
关键词
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资金
- MICINN (Spain) [CTQ2010-15364]
- University of Valencia [UV-INV-AE11-38904]
- Generalitat Valenciana (Spain) [PROMETEO/2009/108, GV/2012/051, ISIC/2012/002]
- MICINN
The novel mononuclear Co(II) complex cis-[Co-II(dmphen)(2)(NCS)(2)]center dot 0.25EtOH (1) (dmphen = 2,9-dimethyl-1,10-phenanthroline) features a highly rhombically distorted octahedral environment that is responsible for the strong positive axial and rhombic magnetic anisotropy of the high-spin Co-II ion (D = +98 cm(-1) and E = +8.4 cm(-1)). Slow magnetic relaxation effects were observed for 1 in the presence of a dc magnetic field, constituting the first example of field-induced single-molecule magnet behavior in a mononuclear six-coordinate Co(II) complex with a transverse anisotropy energy barrier.
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