期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 10, 页码 4497-4500出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2115635
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资金
- Alexander von Humboldt Foundation
- Deutsche Forschungsgemeinschaft (DFG)
Ionothennal reactions of [Ge4Se10](4-) with SnCl4 center dot 5H(2)O yielded [BMMIm](24)[Sn36Ge24Se132] (ZBT-1) and [BMIm](24)[Sn32.5Ge27.5Se132] [ZBT-2; B(M)MIm = 1-butyl-(2,)3-(di)methylimidazolium]. These contain the largest known discrete polyanion consisting only of main-group elements. In spite of a zeolite-related composition, the 192-atom zeoball anion adopts a spherical shape, which has been unprecedented in the chemistry of zeolites and their homologues and relatives. Preliminary studies indicated that ZBT-1 traps 12 molecules and induces heterolytic I I bond cleavage.
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