期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 31, 页码 12912-12915出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja305209w
关键词
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资金
- Spanish Ministerio de Ciencia e Innovacion [CTQ2010-15297, CTQ2010-14974]
- European FEDER funds
- Junta de Andalucia [2008/FQM-3833, 2009/FQM-4537]
- CSIC
The dual activation of alpha-keto esters and formaldehyde tert-butyl hydrazone by BINAM-derived bis-ureas is the key to achieve high reactivity and excellent enantioselectivities in nucleophilic addition (formal carbonyl-ene reaction) to functionalized tertiary carbinols. Ensuing high-yielding diazene-to-aldehyde tranformations and subsequent derivatizations provides a direct entry to a variety of densely functionalized products.
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