期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 37, 页码 15189-15192出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja305634j
关键词
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资金
- 973 Project [2009CB623601, 2009CB930603]
- National Natural Science Foundation of China [20923003, 21174144, 21074130]
- Science Fund for Creative Research Groups [20921061]
In view of the tolerance of F atoms in FIrpic to the nucleophilic aromatic substitution polymerization, an activated fluorinated poly(arylene ether phosphine oxide) backbone is used to construct novel blue electrophosphorescent polymers containing FIrpic as the blue emitter, because they can be synthesized under a milder temperature of 120 degrees C. Compared with the counterparts prepared at high temperature (165 degrees C), unexpected bathochromic shift is successfully avoided, and a state-of-art luminous efficiency as high as 19.4 cd A(-1) is achieved. The efficiency is comparable to the corresponding physical blend system, which indicates that the fluorinated poly(arylene ether phosphine oxide) has the potential to be used as the platform for the development of high-performance all-phosphorescent white polymer based on single polymer system.
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