期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 6, 页码 2860-2863出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja211455j
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资金
- Schlumberger Foundation's Faculty for the Future
- NRSCC
- University of Amsterdam
A chiral supramolecular ligand has been assembled and applied to the rhodium-catalyzed asymmetric hydroformylation of unfunctionalized internal alkenes. Spatial confinement of the metal center within a chiral pocket results in reversed regioselectivity and remarkable enantioselectivities.
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