期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 11, 页码 5048-5051出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja300294a
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资金
- Deutsche Forschungsgemeinschaft
- Studienstiftung des deutschen Volkes
The low-valent iron complex Bu4N[Fe-(CO)(3)(NO)] (TBAFe) catalyzes the allylic C-C-bond activation of electron-poor vinyl cyclopropanes to generate synthetically useful a1,a3,d5-synthons which are prone to undergo multiple consecutive reactions. The versatility of this approach is demonstrated by a traceless allylic substitution and a formal [3 + 2] cycloaddition to give either functionalized acyclic products or densely substituted cyclopentanes and pyrrolidines in high yields and regioselectivities.
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