4.8 Article

Time-Resolved in Situ Neutron Diffraction under Supercritical Hydrothermal Conditions: A Study of the Synthesis of KTiOPO4

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 43, 页码 17889-17891

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AMER CHEMICAL SOC
DOI: 10.1021/ja3088696

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资金

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF)
  2. Ministry of Education, Science and Technology [2010-0002480]
  3. EPSRC

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In the first in situ neutron powder diffraction study of a supercritical hydrothermal synthesis, the crystallization of KTiOPO4 (KTP) at 450 degrees C and 380 bar has been investigated. The time-resolved diffraction data suggest that the crystallization of KTP occurs by the reaction between dissolved K+(aq), PO43-(aq), and [Ti(OH)(x)]((4-x)+)(aq) species.

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