期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 11, 页码 3760-3763出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1112035
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资金
- Hong Kong Research Grants Council [CUHK 402408, 402017]
- Wei Lun Foundation
- Chinese University of Hong Kong
Two neutral silver(I)-phenylethynide clusters incorporating the [((BuPO3)-Bu-t)(4)V4O8](4-) unit as an integral shell component, namely {(NO3)(2)@Ag-16(C CPh)(4)[((BuPO3)-Bu-t)(4)V4O8](2)(DMF)(6)(NO3)(2)}center dot DMF center dot H2O and {[(O-2)V2O6](3)@Ag-43(C CPh)(19)[((BuPO3)-Bu-t)(4)V4O8](3)(DMF)(6)}center dot 5DMF center dot 2H(2)O, have been isolated and characterized by X-ray crystallography. The central cavities of the Ag-16 and Ag-43 clusters are occupied by two NO3- and three [(O-2)V2O6](4-) template anions, respectively.
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