期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 17, 页码 6493-6496出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja110398p
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [21750144] Funding Source: KAKEN
Unprecedented strong phosphorescent emission in the crystalline state is observed for a variety of vaulted trans-bis(salicylaldiminato)platinum(II) complexes which are newly synthesized as a third coordination mode of well-studied bis(salicylaldiminato) complexes. This Communication describes the dynamic photophysical properties of these complexes in the liquid and crystalline states and a mechanistic rationale for the strong emission in the crystalline state.
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