期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 24, 页码 9232-9235出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2031085
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Strategic positioning of a silyl group on the diene unit of a diene-ene substrate allows rigorous regio-and stereocontrol to be exerted during metathesis-based macrocyclization reactions. The versatility of this concise approach to E,Z-configured 1,3-dienes of ring sizes of 12 or larger is demonstrated by an application to the total synthesis of lactimidomycin, a potent translation and cell-migration inhibitor.
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