期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 23, 页码 8854-8857出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja202874d
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资金
- JSPS [20-11673]
- Program for the Promotion of Basic and Applied Research for Innovations in the Bio-oriented Industry (BRAIN)
- Grants-in-Aid for Scientific Research [23390026] Funding Source: KAKEN
Enantiocontrolled total syntheses of the breviones A, B, and C have been accomplished using a highly diastereoselective oxidative coupling of an a-pyrone with a tricyclic diene prepared from an optically pure Wieland-Miescher ketone derivative through the 7-endo-trig mode of acyl radical cyclization.
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