期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 29, 页码 11042-11045出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja203053y
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资金
- National Natural Science Foundation of China [20871088, 90922018]
- Nature Science Key Basic Research of Jiangsu Province for Higher Education [09KJA150002]
- Higher Education of the Ministry of Education [20093201110017]
- State Key Laboratory of Coordination Chemistry of Nanjing University
- Jiangsu Province [333]
- Program for Innovative Research Team of Soochow University
- Universities ofJiangsu Province [CX10B-032Z]
The three-dimensional crystalline porous metal organic framework [Ni(2)(mu(2)-OH(2))(1,3-BDC)(2)(tpcb)](n) (1) [1,3-H(2)BDC = 1,3-benzenedicarboxylic acid; tpcb = tetralds(4-pyridyl)cyclobutane] was used to separate a solid mixture of naphthalene and anthracene at room temperature via selective adsorption of naphthalene. The process involved a single-crystal-to-single-crystal transformation. The guest naphthalene molecules could be exchanged with ethanol, and the host, 1, could be regenerated by removal of the guest ethanol molecules.
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