期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 10, 页码 3410-3418出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja107921a
关键词
-
资金
- NSF of China [20821061, 90922035]
- 973 program [2011CBA00505]
- CAS [KJCX2.YW.M10, KJCX2.YW.319]
- NSF of Fujian Province [2008F3115]
Two inorganic supramolecular compounds, (Hg-6-P-3)(In2Cl9) (1) and (Hg8As4)(Bi3Cl13) (2), which have chiral 3-D host frameworks with guest moieties filling the helical tunnels, have been synthesized. They both have large second-harmonic generation efficiencies, and compound 2 also exhibits obvious single-crystal piezoelectric performance. Theoretical studies from first-principles calculations were performed on their nonlinear optical (NLO) and piezoelectric properties, and results indicate that good NLO and piezoelectric materials can be obtained by designing both complicated polycations and polyanions with large molecular polarizability as components rather than traditional single polyanions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据