期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 31, 页码 10658-10659出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja104938v
关键词
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资金
- U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE) [FC3605G015062]
A new ambient-temperature, catalyst-free reaction between ammonia borane and tetrahydrofuran borane produces aminodiborane via the formation of a dihydrogen bond and subsequent molecular hydrogen elimination. The facile synthesis of aminodiborane will make this long-sought active chemical reagent readily available for both inorganic and organic reactions. From aminodiborane, an inorganic butane analogue, NH3BH2NH2BH3, was prepared, and its single-crystal structure displayed a gauche rather than an anti form conformation.
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