期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 46, 页码 16346-16348出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1072417
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资金
- Ministry of Education, Culture, Sports, Science, and Technology, Japanese Government [21350055]
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [21350055] Funding Source: KAKEN
The combination of Pd catalyst and Xantphos ligand in the presence of Et3B nicely promotes the allylation of aldehydes with conjugated dienes to provide dienyl homoallyl alcohols in excellent yields. The reaction occurs selectively at the C-C double bond bearing higher electron density.
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