期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 22, 页码 7582-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja102323g
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资金
- U.S. DOE Office of Basic Energy Science [DE-AC02-07CH11358]
- ACS Green Chemistry Institute-PRF
An unusual beta-elimination reaction involving zinc(II) and LiCl is reported. LiCl and a coordinatively saturated disilazido zinc compound form an adduct that contains activated SiH moieties. In THF/toluene mixtures, this adduct is transformed into a zinc hydride and 0.5 equiv. cyclodisilazane. The Li+ and Cl- ions apparently affect the reaction pathway of the disilazido zinc in a synergistic fashion. Thus, the zinc hydride and cyclodisilazane products of formal beta-elimination are not observed upon treatment of the zinc disilazide with Cl- or Li+ separately.
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