期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 34, 页码 11825-11827出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1052973
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资金
- CNRS
- University of Nice
Mg in catalytic amounts as the only metal permits the reductive coupling between benzyl halides and pinacolborane. HBpin acts both as an electrophile and as a reducing agent to regenerate an organomagnesium species in situ. An hydride oxidation mechanism is proposed on the basis of DFT calculations.
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