期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 13, 页码 4520-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja9102309
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资金
- NSF [CHE-0848693, CHE-0701247, CHE-0741936]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0741936] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0848693] Funding Source: National Science Foundation
Synthesis and characterization of the monomeric complex ('bpy)Pt(Me)(NHPh) ('bpy = 4,4'-di-tert-butyl-2,2'-dipyridyl) has been accomplished. Mechanistic studies reveal that 1,2-addition of dihydrogen across the Pt-anilido bond to initially produce ('bpy)Pt(Me)(H) and free aniline is catalyzed by elemental Pt rather than through a pathway that involves direct activation of H-2 by Pt and 1,2-addition across the Pt-NHPh bond.
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