期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 9, 页码 3174-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja810142v
关键词
-
资金
- MEXT, Japan
- Nagase Science and Technology Foundation
The rhodium-catalyzed reductive cleavage of carbon-cyano bonds is developed using hydrosilane as a mild reducing agent. A wide range of nitrites, including aryl, benzyl, and B-hydrogen containing alkyl cyanides are applicable to this decyanation reaction. The method can also be applied to organic synthesis; the use of benzyl cyanide as a benzyl anion equivalent and the use of a cyano group as a removable ortho-directing group are demonstrated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据