期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 44, 页码 15994-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja907110e
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资金
- Robert A. Welch Foundation [I-1612, I-1689]
- Chilton Foundation
- NSF
- Sara and Frank McKnight Foundation
A new technique to deconvolute complex H-1 NMR spectra of small molecules has been developed that utilizes shape selective pulses to simultaneously decouple multiple protons. A limitation in the assignment of the relative configuration of small molecules is the ability to accurately obtain coupling constants. Other methods such as the E.COSY and the 2D J-resolved are available to obtain complicated coupling constants; the multiple homonuclear decoupling method (MDEC) described is a rapid and simple technique. Three examples of increasing spectral complexity, menthol, cholesteryl acetate and a C-16 fatty acid, demonstrate the utility of the technique. Increasing the experimental utility, the single pulse MDEC experiment can be incorporated in other 1 D experiments, such as a 1D-TOCSY to solve specific problems.
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