期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 31, 页码 10798-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja902659c
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资金
- Russian Foundation for Basic Research [06-03-32214, 09-03-00087]
The key intermediate of a bioinspired iron catalyst for selective hydrocarbon oxidation based on hydrogen peroxide and an iron complex with a tetradentate aminopyridine ligand was trapped by EPR. On the basis of EPR and reactivity data this intermediate is tentatively proposed to be an oxoiron(V) complex.
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