期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 51, 页码 17226-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja806569h
关键词
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资金
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [19750031]
- NOVARTIS Foundation (Japan) for the Promotion of Science
- Takeda Pharmaceutical Company Award in Synthetic Organic Chemistry, Japan
- Grants-in-Aid for Scientific Research [19750031] Funding Source: KAKEN
An intermolecular nickel-catalyzed addition reaction has been developed where phthalic anhydrides react with alkynes to afford substituted isocoumarins. A mechanistic rationale is proposed, implying reductive elimination of Ni(0) promoted by ZnCl2 cocatalyst as the key step of the catalytic cycle.
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