期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 2, 页码 438-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja078042b
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资金
- National Research Foundation of Korea [과06A1503, R16-1997-011-01001-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
meso-Aryl-substituted subchlorins were obtained as a side product in acid-catalyzed subporphyrin synthesis and were fully characterized. Subchlorins were more efficiently prepared by reduction of subporphyrins with p-losylhydrazide under basic conditions. Structural change from subporphyrin to subchlorin is accompanied by large optical and electrochemical changes that are quite similar to those observed upon change from porphyrin to chlorin. Optical and electrochemical properties of subchlorins are well understood with the framework of Gouterman's four-orbital theory.
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