期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 43, 页码 14062-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja805921f
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资金
- Ministry of Education, Culture, Sports, Science, and Technology of Japan
- Sumitomo Foundation
- Meiji Seika Co.
- Okayama Foundation for Science and Technology
Treatment of an a,p-unsaturated ketimine with an alpha,beta-unsaturated carbonyl compound in the presence of a rhenium complex, Re-2(CO)(10), gave a cyclopentadienyl-rhenium complex. This reaction proceeds via rhenium-catalyzed C-H bond activation of an olefinic C-H bond, insertion of an alpha,beta-unsaturated carbonyl compound into a Re-C bond of the alkenylrhenium intermediate, intramolecular nucleophilic cyclization, reductive elimination, elimination of aniline to give a cyclopentadiene derivative, followed by the formation of a cyclopentadienyl-rhenium complex from the cyclopentadiene derivative and the rhenium complex.
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