期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 37, 页码 12472-12476出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja803605m
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资金
- NSF [CHE-0111558, 9974875, 0116492, 0320669]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [9974875, 0320669] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0116492] Funding Source: National Science Foundation
The complex TpW(NO)(PMe3)(eta(2)-anisole)is combined with acrolein or methyl vinyl ketone and various nucleophiles to generate novel chromen complexes. These complexes may be further elaborated by protonation and nucleophilic addition to generate chroman analogues with increased saturation and stereocenters. Treatment with various oxidants effects the decomplexation of the chromen.
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