期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 22, 页码 6894-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja710423d
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In an exploration of six coordination and hypervalence in carbon compounds, steric constraints have been employed to bring four ether O atoms in close proximity to an allenic carbon atom. The dimethylated dication 2 is confirmed to have hexacoordinate carbon by experimental charge density analysis and DFT calculations and is arguably hypervalent.
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