期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 52, 页码 17681-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja807504k
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资金
- Agence Nationale de la Recherche [ANR-06-BLAN-0295]
- Agence Nationale de la Recherche (ANR) [ANR-06-BLAN-0295] Funding Source: Agence Nationale de la Recherche (ANR)
The bridging of distyryl-bithiophene leads to a kite shape of the conjugated system. This twist is not like twistacenes or twist deformation in alpha-oligothiophenes but a curvature such as in bowl shaped systems. Initially perceived to be undesirable, this new semiconductor in OTFT devices provides excellent performances in air, mu = 0.1 cm(2)/V.s, I-on/I-off > 10(6), S < 4 V/decade, higher by a factor of 5 to the parent unbridged coplanar analogue.
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