期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 45, 页码 14944-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja805900e
关键词
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资金
- European Union [STRP 516982]
- ESF [Eurocores-05SONS-FP-021]
- Spanish Ministry of Science and Innovation (MICINN [MAT2006-28185-E, MAT2007-61584, CSD2007-00010, CTQ2006-14987-C02-02]
- Generalitat Valenciana
- European FEDER funds
- Swiss National Science Foundation
- Swiss National Center of Competence in Research
- Ramon y Cajal
- FPU
A new iridium(III) complex showing intramolecular interligand pi-stacking has been synthesized and used to improve the stability of single-component, solid-state light-emitting electrochemical cell (LEC) devices. The pi-stacking results in the formation of a very stable supramolecularly caged complex. LECs using this complex show extraordinary stabilities (estimated lifetime of 600 h) and luminance values (average luminance of 230 cd m(-2)) indicating the path toward stable ionic complexes for use in LECs reaching stabilities required for practical applications.
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