4.3 Article

Facile Synthesis of Co3O4/CoO Nanoparticles by Thermal Treatment of Ball-Milled Precursors

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DOI: 10.1007/s10948-011-1141-5

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Cobalt oxides; Nanoparticles; Ball mill; X-ray diffraction

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  1. Isfahan University of Technology

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Co3O4/CoO nanoparticles have been synthesized by a simple method which is based on the ball-milling and calcination of cobalt acetate and citric acid. The samples were characterized using X-ray diffraction, transmission electron microscope, and Fourier transform infrared spectroscopy. The results show that Co3O4 nanoparticles with an average particle size of similar to 40 nm can be obtained by calcination of ball-milled precursors at relatively low temperature (350 A degrees C) for 3 hours. It should be noted that it is possible to control the size of Co3O4 particles by calcination temperature, calcination time and also by ball-milling duration using this method. Meanwhile, the pure CoO nanoparticles were obtained successfully by thermal decomposition of Co3O4 at 950 A degrees C and quickly quenching to liquid nitrogen.

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