Article
Chemistry, Physical
Yusuke Shimoda, Yukiko Matsui, Takeshi Tonoya, Masashi Ishikawa
Summary: Lithium-sulfur (Li-S) batteries are promising for high energy density applications, but the dissolution of Li polysulfides in the electrolyte hinders their practical use. The addition of a highly concentrated sulfolane-based electrolyte can solve this problem, but it decreases the reversibility of the Li-metal anode. By adding potassium FSI (KFSI) as an electrolyte additive, a stable solid electrolyte interface (SEI) can be formed at the Li anode, significantly improving the Coulombic efficiency and cycle stability of Li-S batteries. These results demonstrate the effectiveness of KFSI in protecting Li-metal anodes and enhancing the performance of Li-S batteries.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Electrochemistry
Yan Yuan, Zhengqian Li, Xiuping Peng, Kesi Xue, Manbo Liu, Zhao Fang, Lianli Wang, Huiling Du, Hai Lu
Summary: A novel PS gel cathode, which integrates a functional polymer gel network into carbon cloth as the supporting matrix, effectively addresses the drawbacks of Lithium-polysulfide semiflow battery. The unique cell configuration demonstrates increased reversible capacity, sustainable long-term cycling stability, and superior rate capability.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Physical
Bo Fan, Zebo Guan, Hongjiao Wang, Lilin Wu, Wenzhi Li, Shibang Zhang, Bai Xue
Summary: This study quantitatively investigated the evolution of electrochemical impedance spectra of all-solid-state lithium-sulfur batteries, revealing the characteristics of different interfaces and dynamic processes within the battery. The analysis of impedance spectra indicated that Li diffusion plays a significant role in charge transfer within the active materials.
SOLID STATE IONICS
(2021)
Article
Chemistry, Physical
Xiaoshi Lang, Ruiyin Ren, Xinxi Wang, Lan Li, Kedi Cai
Summary: Cu2+ regulated Fe2O3 nanospheres were prepared as high-performance matrixes for sulfur composite cathodes of lithium-sulfur batteries via a facile hydrothermal method, effectively solving the issues of sulfur insulation, volume alternation, and shuttle effect.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Andreas Strasser, Alexander Adam, Jiahao Li
Summary: Reducing the charging time is important for increasing the acceptance of electric vehicles. This paper introduces a new method that allows the detection of the onset of lithium plating in automotive lithium-ion batteries using online electrochemical impedance spectroscopy. The detection is based on observing the real part of the impedance across the state of charge during the charging procedure.
JOURNAL OF POWER SOURCES
(2023)
Article
Materials Science, Ceramics
Jian Wei, Bing Chen, Huan Su, Chao Jiang, Xueting Li, Shishuai Qiao, Hao Zhang
Summary: The lithium-sulfur battery is a promising energy storage device with high energy density and environmental friendliness, but challenges exist in solving the electrical insulation of sulfur and the dissolution of intermediates in the electrolyte. A novel Co9S8@S/GO hybrid has been developed as a host for the sulfur cathode, which shows better electrochemical performance by capturing polysulfides through physical and chemical adsorption with graphene oxide and polar hollow Co9S8 nanotube.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Yu-Hong Liu, Lan-Xing Li, An-Yi Wen, Fei-Fei Cao, Huan Ye
Summary: A thin (MXene/PP/Cu-TCPP) Janus separator was designed to address the rapid capacity fading and poor safety of lithium-sulfur batteries. The separator had an anisotropic spatial heterogeneity, with a sulfophile cathode-facing surface and a multifunctional ionic sieve on the opposite side. The MXene layer acted as an expanded S host, confining sulfur and its intermediates, while the MOF layer served as an ionic sieve and prevented dendritic growth of Li.
ENERGY STORAGE MATERIALS
(2023)
Article
Electrochemistry
Alexander Ridder, Benedikt Prifling, Andre Hilger, Markus Osenberg, Matthias Weber, Ingo Manke, Kai Peter Birke, Volker Schmidt
Summary: In this paper, cyclically aged lithium-ion batteries are characterized by a statistical 3D microstructure analysis and electrochemical properties. Synchrotron tomography is used to capture the morphology of the cathodes with different state of health. The 3D microstructure is quantitatively characterized by phase-based and particle-based characteristics, and the electrochemical data is correlated with the detected structural changes. This is the most extensive data set of cyclically aged lithium-ion cells including both electrochemical data and 3D structures.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Chang-Heum Jo, Natalia Voronina, Seung-Taek Myung
Summary: This article discusses the technical challenges in the synthesis, morphology control, stability, and surface modification of high-energy-density single-crystalline particle Ni-based cathode materials for lithium-ion batteries.
ENERGY STORAGE MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Ruili Gao, Shan Ji, Fanghui Wang, Kunpeng Wang, Hui Wang, Xianguo Ma, Vladimir Linkov, Xuyun Wang, Rongfang Wang
Summary: In this study, perylenequinone was used to enhance polysulfide chemisorption and conversion on cobalt-containing Li-S battery cathodes. The newly prepared cathode material exhibited excellent rate and cycling performances.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Applied
Dominika Capkova, Vaclav Knap, Andrea Strakova Fedorkova, Daniel-Ioan Stroe
Summary: This study characterizes the impedance behavior of lithium-sulfur batteries using electrochemical impedance spectroscopy (EIS) and investigates the effects of temperature and superimposed AC current on impedance. The results provide insights into the electrochemical reactions and resistance changes in lithium-sulfur batteries.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Chemistry, Physical
Jidapa Lomon, Jintara Padchasri, Amorntep Montreeuppathum, Sumet Siriroj, Yingyot Poo-arporn, Supree Pinitsoontorn, Prayoon Songsiriritthigul, Saroj Rujirawat, Pinit Kidkhunthod, Narong Chanlek
Summary: In this study, the effect of nickel content in lithium borate (LiBO3) glass systems on the performance of cathode materials for Li-ion batteries was investigated. It was found that increasing the nickel content enhanced the electrochemical properties of the glass. The 0.25Ni:LiBO3 glass electrode showed the highest specific capacitance, indicating its potential as a promising battery material.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Binwei He, Zhengyu Wang, Guoran Li, Sheng Liu, Xueping Gao
Summary: This study introduces a method of using perovskite transition metal oxide LaFeO3 as a host material in the sulfur cathode, which has high tap density and excellent electrical conductivity. LaFeO3 nanofibers prepared by electrospinning not only have remarkable electron and ion-conducting networks, but also exhibit excellent chemical adsorption and catalytic activities for soluble lithium polysulfides. As a result, the sulfur/LaFeO3 composite shows a low capacity decay rate and a high initial discharge capacity, providing a promising strategy for high-performance Li-S batteries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Electrochemistry
Kazuki Yoshii, Kazushige Kohno, Yuta Maeyoshi, Noboru Taguchi, Akira Yano, Tomonari Takeuchi, Hikari Sakaebe
Summary: This study investigated the charge and discharge behavior of a low-crystalline VS4 positive electrode using different electrolytes and under differing charge and discharge conditions. The electrolyte composed purely of cyclic carbonate displayed higher cycle performance than the one containing linear carbonate. Addition of fluoroethylene carbonate (FEC) to the electrolyte effectively improved the cycle performance. The results showed that LiF-containing components were formed on the VS4 surface, which contributed to the improvement of the charge and discharge behavior of the VS4 positive electrode.
BATTERIES & SUPERCAPS
(2022)
Review
Chemistry, Physical
Yu Jiao, Fan Wang, Yuhong Ma, Sangang Luo, Yaoyao Li, Anjun Hu, Miao He, Fei Li, Dongjiang Chen, Wei Chen, Tianyu Lei, Yin Hu
Summary: This review categorizes the basic failure mechanisms and major challenges of Li-S batteries at low temperature, and discusses strategies and advances in the design of optimized electrolyte, composite cathode and functional separator. Suggestions for future development of practical Li-S batteries at low temperature are proposed.
Article
Chemistry, Physical
Yongguang Zhang, Yan Zhao, Aishuak Konarov, Zhi Li, P. Chen
JOURNAL OF ALLOYS AND COMPOUNDS
(2015)
Article
Chemistry, Physical
Mingqi Li, Yan Yu, Jing Li, Baoling Chen, Aishuak Konarov, P. Chen
JOURNAL OF POWER SOURCES
(2015)
Article
Electrochemistry
Aishuak Konarov, Denise Gosselink, Yongguang Zhang, Ye Tian, Diana Askhatova, P. Chen
ECS ELECTROCHEMISTRY LETTERS
(2015)
Article
Chemistry, Physical
Aishuak Konarov, Zhumabay Bakenov, Hitoshi Yashiro, Yang-Kook Sun, Seung-Taek Myung
JOURNAL OF POWER SOURCES
(2017)
Editorial Material
Chemistry, Physical
Aishuak Konarov, Seung-Taek Myung, Yang-Kook Sun
ACS ENERGY LETTERS
(2017)
Article
Chemistry, Multidisciplinary
Jae Hyeon Jo, Ji Ung Choi, Aishuak Konarov, Hitoshi Yashiro, Shuai Yuan, Liyi Shi, Yang-Kook Sun, Seung-Taek Myung
ADVANCED FUNCTIONAL MATERIALS
(2018)
Article
Chemistry, Physical
Aishuak Konarov, Ji Ung Choi, Zhumabay Bakenov, Seung-Taek Myung
JOURNAL OF MATERIALS CHEMISTRY A
(2018)
Article
Chemistry, Physical
Yongguang Zhang, Zhumabay Bakenov, Yan Zhao, Aishuak Konarov, Qiang Wang, P. Chen
Article
Chemistry, Physical
Aishuak Konarov, Denise Gosselink, The Nam Long Doan, Yongguang Zhang, Yan Zhao, P. Chen
JOURNAL OF POWER SOURCES
(2014)
Article
Chemistry, Physical
Yongguang Zhang, Yan Zhao, Zhumabay Bakenov, Aishuak Konarov, P. Chen
JOURNAL OF POWER SOURCES
(2014)
Review
Chemistry, Physical
Aishuak Konarov, Natalia Voronina, Jae Hyeon Jo, Zhumabay Bakenov, Yang-Kook Sun, Seung-Taek Myung
ACS ENERGY LETTERS
(2018)
Article
Chemistry, Physical
Hee Jae Kim, Aishuak Konarov, Jae Hyeon Jo, Ji Ung Choi, Kyuwook Ihm, Han-Koo Lee, Jongsoon Kim, Seung-Taek Myung
ADVANCED ENERGY MATERIALS
(2019)
Article
Chemistry, Multidisciplinary
Nurzhan Baikalov, Islam Rakhimbek, Aishuak Konarov, Almagul Mentbayeva, Yongguang Zhang, Zhumabay Bakenov
Summary: Despite being the most theoretically efficient and cost-effective rechargeable batteries, lithium-sulfur batteries face challenges due to the low conductivity of sulfur and the polysulfide shuttle effect. This study focuses on modifying the separator of Li-S batteries with Ni nanoparticles encapsulated in nitrogen-doped graphene supported by nitrogen-doped graphitic carbon (Ni@NGC) to improve their performance. By controlling the loading of Ni, the surface area-to-metal content ratio can be adjusted to influence the reaction kinetics and cycling performance of Li-S cells.
Review
Chemistry, Multidisciplinary
Lunara Rakhymbay, Bagdaulet Shugay, Maksat Karlykan, Alibi Namazbay, Aishuak Konarov, Zhumabay Bakenov
Summary: There is a growing focus on different technologies used in energy production and storage, ranging from small-scale to large-scale applications, which are equally important. Li-ion batteries are currently the market leader in energy storage systems due to their high energy and power density. However, the scarcity of lithium resources and other metals for cathode materials in the long run is a significant concern. Recent research has looked into alternative energy storage systems, and sodium-ion batteries (SIBs) are considered the most promising next-generation alternative due to sodium's widespread availability and similar chemistry to lithium-ion batteries. The Na2Mn3O7 electrode has shown high capacity as a cathode material and is particularly attractive due to the low price of sodium and manganese. This work summarizes the recent progress in studying and enhancing the Na2Mn3O7 cathode material.
EURASIAN JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Physical
Aishuak Konarov, Hee Jae Kim, Hitoshi Yashiro, Seung-Taek Myung
JOURNAL OF MATERIALS CHEMISTRY A
(2019)