期刊
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
卷 17, 期 6, 页码 1505-1508出版社
SPRINGER
DOI: 10.1007/s10008-013-2119-y
关键词
Electrodeposition; Nucleation; Growth; Diffusion; Galvanostatic conditions
A theory is proposed for galvanostatic three-dimensional nucleation and growth of new phase clusters controlled by diffusion of depositing ions in the bulk of the electrolyte to the clusters surface. The mathematical model is used to calculate the time dependences of the overpotential, number, and size of clusters formed on the electrode.
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