期刊
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
卷 15, 期 11-12, 页码 2695-2702出版社
SPRINGER
DOI: 10.1007/s10008-010-1197-3
关键词
Multiwalled carbon nanotube; 5-Br-PADAP; Lead(II); Stripping voltammetry
The present study serves to focus attention on the modification of multiwalled carbon nanotube with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (5-Br-PADAP) and its application for the development of a new, simple, and selective modified electrode in order to determine Pb(II) in standard alloys and water samples. The electrochemical method was based on open circuit accumulation of lead ions onto a 5-Br-PADAP-modified multiwalled carbon nanotube electrode and then their anodic stripping voltammetric determination. The linear range for Pb(II) ions was from 0.9 to 114.6 mu g L-1. The detection limit and relative standard deviation were found to be 0.1 mu g L-1 and 1.6%, respectively. This method demonstrates the powerful application of carbon nanotubes in the field of mercury-free electrodes in voltammetric stripping analysis.
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