4.6 Article

Controlled synthesis of T-shaped BiVO4 and enhanced visible light responsive photocatalytic activity

期刊

JOURNAL OF SOLID STATE CHEMISTRY
卷 211, 期 -, 页码 176-183

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2013.12.027

关键词

T-shaped BiVO4; Hydrothermal method; Methylene Blue; Photocatalytic; Visible light

资金

  1. Basic Scientific and Technological Frontier Project of Henan Province, PR China [102300410193, 132330410138, 122300410293]
  2. Innovation Scientists and Technicians Troop Construction Projects of Henan Province
  3. Plan for Scientific Innovation Talent of Henan Province [134200510014]

向作者/读者索取更多资源

A novel T-shaped BiVO4 microcrystal photocatalyst was successfully synthesized by the hydrothermal method with the aid of a structure-directing surfactant SOBS in the present study. Having received well characterization with the aid of various techniques and the results showed that the SOBS greatly changed the microstructure of BiVO4, which had a unique T shape and belonged to the monoclinic family. The fast exchange dynamics between the surfactants bound to the Bi3+ seed surface and the free VO3- in the solution significantly increase the rate of heterogeneous nucleation. In addition, the photocatalytic activity of the prepared T-shaped BiVO4 was evaluated by the degradation of Methylene Blue solution under visible light irradiation, 17% and 47% higher decolorization rates than the commercial P25 and BiVO4 synthesized without SOBS, respectively. Meanwhile, it has been found that the degradation kinetics of MB fitted the pseudo-first-order kinetics and the T-shaped BiVO4 also displayed high photocatalytic performance for metronidazole degradation. (C) 2014 Elsevier Inc. All rights reserved.

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