4.6 Article

Topotactic synthesis of Co3O4 nanoboxes from Co(OH)2 nanoflakes

期刊

JOURNAL OF SOLID STATE CHEMISTRY
卷 184, 期 11, 页码 2961-2965

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2011.08.026

关键词

Solvothermal synthesis; Crystal morphology; Topotactic growth

资金

  1. China Postdoctoral Science Foundation [20100480947, 201104510]
  2. Postdoctoral Science Foundation of Central South University of China [1332-74341015511]
  3. Hunan University of Science and Technology [E51079, G30953]

向作者/读者索取更多资源

Hollow nanocubes of spinel Co3O4 with the dimension of 20 nm were successfully prepared via a facile and reproducible solvothermal route. The structure and morphology of Co3O4 nanoboxes were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and high-resolution transmission electron microscope (HRTEM) techniques. And a possible growth mechanism of Co3O4 nanoboxes were suggested that solid Co3O4 nanocubes nucleate in-situ and grow epitaxially from hexagonal beta-Co(OH)(2) precursors with the structural matching relationship of [0 0 1] beta-Co(OH)(2)//[1 1 1] Co3O4, and then solid Co3O4 nanocubes gradually hollow and convert to single-crystal nanoboxes owing to Ostwald ripening. (C) 2011 Elsevier Inc. All rights reserved.

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