Article
Materials Science, Multidisciplinary
M. Anas, T. Maitra, V. K. Malik
Summary: The orthovanadate DyVO3 was synthesized by reducing DyVO4 in a hydrogen environment. It has an orthorhombic crystal structure (space group Pbnm) at room temperature. The antiferromagnetic transition of the vanadium sublattice occurs around 114 K. The effect of an external magnetic field on spin re-arrangement in the vanadium sublattice has been studied, and the maximum magnetic entropy change and relative cooling power have been calculated.
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2023)
Article
Crystallography
Zanlin Qiu, Joerg R. R. Jinschek, Pelagia-Irene Gouma
Summary: This study presents a reliable method for obtaining hexagonal tungsten trioxide (h-WO3) through solvothermal synthesis and dehydration annealing, and investigates the effects of precursor concentration, water content, synthesis temperature, synthesis time, and dehydration temperature on the crystal structure and morphology of the synthesized h-WO3.
Article
Chemistry, Physical
Benfu Qian, Ze Wang, Yulu Wang, Qianran Zhao, Xiuqing Zhou, Haifeng Zou, Yanhua Song, Ye Sheng
Summary: This study obtained rod-like Lu2O2S:Eu3+, cylindrical Gd2O2S:Eu3+, and irregular Y2O2S:Eu3+ phosphors through solvothermal synthesis and subsequent calcination process. The formation mechanisms of different morphologies, as well as the luminescent properties, were discussed and analyzed in detail. The results indicate that matrix cation has a significant effect on morphology control under high pH conditions. Various growth processes were studied for the different morphologies.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Ming Sun, Isabelle Ly, Wilfrid Neri, Ahmed Bentaleb, Jinkai Yuan
Summary: The study synthesized TiO2 nanoparticles with adjustable shape, size, and crystal structures through hydrolysis, achieving an optimal TiO2 nanosheet and observing the formation of a liquid crystal phase. This work provides valuable insight for the fabrication of TiO2 nanostructures for potential applications in diverse fields.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Crystallography
Yanyan Xu, Yaru Fan, Xin Tian, Yaqiu Sun
Summary: In this study, three types of ZnO nanostructures were successfully prepared by a solvothermal method, showing different morphologies as the water content in the solvent increased. The size of the nanostructures could be tuned by adjusting the amount of sodium acetate. The unique morphology of the as-synthesized ZnO nanostructures exhibited good gas response and fast response towards n-butanol gas, showing a clear size-dependent effect.
JOURNAL OF CRYSTAL GROWTH
(2021)
Article
Chemistry, Physical
Maria Batuk, Daphne Vandemeulebroucke, Monica Ceretti, Werner Paulus, Joke Hadermann
Summary: This paper presents the first ever in situ 3D electron diffraction (ED) experiment in a gas environment, investigating the structure evolution of SrFeO2.5 material. The results show that SrFeO2.5 undergoes transformation into SrFeO2.75 and SrFeO3-delta structures under O-2 flow. However, during the reduction process in H-2 flow, the crystals return to their initial structure but without regaining the complete ordered structure.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Multidisciplinary Sciences
Lin Zhang, Li Peng, Yuanchao Lu, Xin Ming, Yuxin Sun, Xiaoyi Xu, Yuxing Xia, Kai Pang, Wenzhang Fang, Ning Huang, Zhen Xu, Yibin Ying, Yingjun Liu, Yingchun Fu, Chao Gao
Summary: This paper presents a wet-interfacial Joule heating approach for synthesizing nanomaterials in a fast, programmable, and energy-saving manner. By confining Joule heat at the substrate-solution interface and inducing instantaneous solvent evaporation, the method accelerates and controls the nucleation and growth of nanomaterials. It achieves high crystallization rates, low energy costs, and low precursor concentrations.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Prasad Walimbe, Masaki Itatani, Preeti Kulkarni, Istvan Lagzi, Sunil Kulkarni
Summary: This study investigates the effect of outer electrolyte concentration and volume on the spacing coefficient in Liesegang phenomenon. The spacing coefficient was found to be dependent on the volume and concentration of the outer electrolyte. It was suggested that the amount of chemical substance and the average molar diffusion flux of the outer electrolyte ions can be used as a unified quantity to express the MP law.
Article
Chemistry, Applied
Xingxu Lu, Meilin Li, Son Hoang, Steven L. Suib, Pu-Xian Gao
Summary: TiO2 nanoarrays grown heterogeneously on substrate surfaces prefer solvents with moderate dielectric constants, which can be partially dissolved in aqueous solution and modulate reaction rates during solvothermal synthesis. Organic solvents with low dielectric constants may lead to a complete separation between precursors and aqueous solution, slowing down the overall reaction and causing insufficient growth of nanoarrays. The optimal morphology for TiO2 nanoarrays, with high specific surface areas and including cordierite substrate, is achieved through a combination of 2-butanone and titanium (IV) butoxide as solvent and precursor, respectively.
Article
Crystallography
Jian Zhang, Lei Zhao, Hongyu Li, Fugui Lei, Liqing Qiao
Summary: In this study, TaC whiskers were successfully synthesized using a halide-assisted carbothermal reduction method, and it was found that their growth occurs via a vapor-liquid-solid mechanism. The synthesized whiskers have a single-crystalline structure and a unique core-shell-like morphology, which can enhance the structural stability of the TaC matrix.
JOURNAL OF CRYSTAL GROWTH
(2021)
Article
Chemistry, Physical
Juan-Juan Shao, Jian-Ling Ni, Yu Liang, Xiu-Dian Xu, Fang-Ming Wang
Summary: A new 3D luminescent Zinc (II) metal-organic framework, compound 1, with a double interpenetrating structure, has been synthesized by solvothermal method. It shows high selectivity and sensitivity in detecting Fe3+ ions in aqueous solution, and is also a highly selective sensing material for CrO42- and Cr2O72- ions.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Physical
Xinyao Shan, Binghan Li, Botao Ji
Summary: This study successfully synthesized monodisperse wurtzite InP quantum dots through cation exchange reaction and demonstrated the feasibility of using this method to synthesize other III-V wurtzite QDs. Additionally, the growth of a gradient ZnSeS shell on wurtzite InP QDs resulted in fluorescent QDs with controllable emission wavelengths.
CHEMISTRY OF MATERIALS
(2021)
Review
Materials Science, Ceramics
Lu Liu, Shuzhong Wang, Guanyu Jiang, Baoquan Zhang, Jianqiao Yang, Jinglong Wang, Wei Liu, Yanhui Li, Hui Liu
Summary: This paper provides a comprehensive review of solvothermal synthesis of nano-zirconia. The reactors and systems used in recent years are introduced, and the advancement of continuously flowing microreactors and field-coupled systems is analyzed. The influencing factors of zirconia solvothermal synthesis are discussed, and the effects of solvents on the synthesis of nano-zirconia products are clarified. The design and mechanism of solvothermal synthesis of different dimensional zirconia nanostructures are revealed, and potential applications and challenges for future research directions are presented.
CERAMICS INTERNATIONAL
(2022)
Article
Biochemistry & Molecular Biology
Monica-Cornelia Sardaru, Narcisa Laura Marangoci, Sergiu Shova, Dana Bejan
Summary: A series of neutral mononuclear lanthanide complexes were synthesized using a rigid bidentate ligand under solvothermal conditions, all of which showed isostructural compounds crystallized in a monoclinic space group. Solid-state luminescence measurements revealed that the [Eu(HL)(2)(NO3)(3)] complex exhibited characteristic emission peaks of Eu(III) ion at 593, 597, 615, and 651 nm.
Article
Crystallography
Hui Liu, Yuanzheng Zhu, Jie Ma, Chunguang Chen, Ping Cheng, Shuping Zhang
Summary: In this study, different amounts of Pd-doped CeO2 nanomaterials were synthesized by a hydrothermal method and characterized. The results show that doping Pd can enhance the catalytic activity of CeO2, and the CeO2 sample with 5% Pd doping exhibits the best electrochemical detection capability for phenol.
JOURNAL OF CRYSTAL GROWTH
(2022)
Article
Chemistry, Multidisciplinary
Na Tao, Huihuang Li, Liu Deng, Senfeng Zhao, Jiang Ouyang, Mei Wen, Wansong Chen, Ke Zeng, Chuanwan Wei, You-Nian Liu
Summary: The study presents a multifunctional platform based on Au nanoparticles and carbon dots modified hollow black TiO2 nanosphere for reversing immunosuppression and alleviating hypoxia in the tumor microenvironment. This platform effectively kills tumor cells by eliciting immune infiltration, alleviating hypoxia, and improving sonodynamic therapy efficiency.
Review
Engineering, Chemical
Jiajia Wang, Lizhi Wang, You Wang, Du Zhang, Qin Xiao, Jianhan Huang, You-Nian Liu
Summary: Carbon capture, storage, and utilization (CCSU) is an effective method for reducing CO2 emissions. Amine aqueous solutions are efficient for CO2 capture due to their large capacity and high selectivity. However, solid adsorbents have gained attention in recent years for CO2 adsorption due to their simplicity and high efficiency. Porous organic polymers (POPs) have shown promise as solid adsorbents for CO2 capture due to their high surface area, adjustable pore size, and easy functionalization. This review provides a detailed overview of different POPs developed in recent years, discussing their design strategies, unique structures, and highlighting the opportunities and challenges associated with POPs.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Du Zhang, Jiajia Wang, You Wang, Yiwen Cao, Jiawei Li, Fa Zhou, Jianhan Huang, You-Nian Liu
Summary: Massive emissions of CO2 and aquatic Hg2+ have caused environmental harm. Melamine-based porous materials with high BET surface area and nitrogen content are beneficial for CO2 capture and Hg2+ removal. In this study, three aromatic ketones were used as monomers to synthesize three aromatic ketone-based melamine-knitted polymers. The polymers exhibited excellent CO2 adsorption and Hg2+ removal performance.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Jia Zheng, Wei Wang, Xinyu Gao, Senfeng Zhao, Wansong Chen, Jianghua Li, You-Nian Liu
Summary: A nanomotor based on L-arginine and gold nanoparticles has been fabricated, which utilizes a cascade catalytic reaction to generate hydrogen peroxide for the oxidation of L-arginine and release of nitric oxide, resulting in self-propelled movement. This nanomotor is capable of efficiently penetrating bacterial biofilm, clearing bacterial infections, and combating MRSA biofilm in vivo.
Article
Nanoscience & Nanotechnology
Tianxing Xu, Qiaoling Yang, Xueliang Zhang, Yin Lin, Jue Wang, Yajuan Li, You-Nian Liu
Summary: This research successfully addresses the low specific capacity of carbon nanotubes (CNTs) by combining organic acetyl groups on unzipped CNTs, resulting in improved electrochemical performance in lithium-ion batteries (LIBs).
ACS APPLIED NANO MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Xinyu Gao, Yihong Liu, Yuqing Li, Bowen Jin, Peixi Jiang, Xi Chen, Chuanwan Wei, Jianping Sheng, You-Nian Liu, Jianghua Li, Wansong Chen
Summary: In this study, MoSe2 nanoflowers (NFs) were utilized as piezoelectric nanozymes for the dual-driven catalytic eradication of multi-drug-resistant bacterial biofilms. The piezoelectricity of MoSe2 NFs, combined with their enzyme-mimic activity, led to a significant increase in oxidative stress in the biofilms under ultrasound irradiation, resulting in a 4.0 log10 reduction of bacterial cells. In vivo studies showed that the MoSe2 NFs effectively reduced the burden of methicillin-resistant Staphylococcus aureus in mice under ultrasound control. Additionally, the surface coating of antioxidant poly(ethyleneimine) minimized off-target damage and promoted wound healing.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Yang Chen, Ting He, Qiming Liu, Yongfeng Hu, Hao Gu, Liu Deng, Hongtao Liu, Youcai Liu, You-Nian Liu, Yi Zhang, Shaowei Chen, Xiaoping Ouyang
Summary: Single-atom catalysts with adjacent Fe nanoclusters supported on nitrogen-doped carbon aerogels show enhanced oxygen reduction reaction activity and anti-oxidation stability, resulting from increased 3d electron density and decreased magnetic moment of Fe atomic centers. A flexible zinc-air battery using these catalysts achieves remarkable performance, even at -40 degrees C, with high open circuit voltage, power density, and excellent durability after 2300 continuous cycles. These results highlight the significance of electronic manipulation in enhancing the durability of single atom catalysts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Engineering, Environmental
Du Zhang, Yiping Chen, Jiajia Wang, You Wang, Yiwen Cao, Jiawei Li, Fa Zhou, Jianhan Huang, You-Nian Liu
Summary: In the Friedel-Crafts acylation, a mixture of carbon disulfide and nitrobenzene was used as the solvent, and (CF3SO3)2Sn was employed as the catalyst to prepare carbonyl-rich polymers. These polymers exhibited moderate surface area, pore volume, and microporosity, and were further functionalized with melamine to enhance their properties. The resulting polymers had higher surface area, pore volume, and nitrogen content, and exhibited efficient adsorption of iodine vapor and mercury ions.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Yanan Li, Yan Wang, Wei Wang, Xiao Yu, Li Zhang, Liu Deng, You-Nian Liu
Summary: Development of heterojunction is an effective strategy to enhance the hydrogen production performance of photocatalysts. In this study, a 2D/2D Z-scheme heterojunction-coupled Zn0.4Cd0.6S with g-C3N4 was fabricated using in situ hydrothermal approach. The sheet-on-sheet architecture allowed full contact of heterojunction, facilitating interfacial charge transfer and increasing surface-active sites. Moreover, the Zn-N coordination bond provided a strong interfacial interaction and spatially separated photogenerated charges along the Z-scheme mechanism. The optimal photocatalyst exhibited high hydrogen production rates (7.69 mmol g-1 h-1) under visible-light irradiation without any cocatalysts, four times higher than the g-C3N4 photocatalyst with Pt as a cocatalyst. The catalyst also showed long-term stability of up to 50 hours. Thus, a direct Z-scheme heterojunction with intimate contact and a well-definite bridging chemical bond holds promise for hydrogen generation.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Engineering, Chemical
Yiwen Cao, Juan Zhong, Zhongke Dai, You Wang, Yuli Fu, Fa Zhou, Jianhan Huang, You-Nian Liu
Summary: In this study, three phenolic hydroxyl aromatic compounds were used as chemical modifiers and incorporated into initial polymers via nucleophilic substitution, resulting in intermediates with different phenolic hydroxyls. Friedel-Crafts alkylation was then used to create multiple phenolic hydroxyl modified hyper-cross-linked polymers. The final polymers exhibited high surface area, large pore volume, and abundant phenolic hydroxyls. These results provide valuable insights into the synthesis and application of chemically modified polymers for enhanced adsorption performance.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Engineering, Chemical
Yanan Li, Yan Wang, Wei Wang, Xiao Yu, Li Zhang, Liu Deng, You-Nian Liu
Summary: Development of heterojunction is an effective strategy to improve the hydrogen production performance of photocatalysts. The fabrication of a 2D/2D Z-scheme heterojunction-coupled Zn0.4Cd0.6S with g-C3N4 by in situ hydrothermal approach is reported in this study. The heterojunction with full contact and strong interfacial interaction enhances the charge transfer and spatial separation of photogenerated charges. Under visible-light irradiation, the optimized catalyst exhibits high hydrogen production without any cocatalysts, outperforming the g-C3N4 photocatalyst with Pt cocatalyst. The catalyst also shows good long-term stability, making it a promising photocatalyst for hydrogen generation.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Na Tao, Lei Jiao, Huihuang Li, Liu Deng, Wei Wang, Senfeng Zhao, Wansong Chen, Limiao Chen, Chengzhou Zhu, You-Nian Liu
Summary: This study demonstrates a mild hyperthermia-enhanced pyroptosis-mediated immunotherapy based on hollow carbon nanozyme, which can amplify anticancer responses in the tumor microenvironment and has implications for clinical immunotherapy.
Article
Chemistry, Physical
Wei Wang, Yan Wang, Jia Zheng, Xiao Yu, Wansong Chen, Jianghua Li, You-Nian Liu
Summary: Solar-driven clean water production has unique advantages in sustainability and environmental friendliness. This study presents an efficient solar-driven vapor generator (SVG) by combining polyvinyl alcohol hydrogel with Prussian blue, which demonstrates excellent water transport and light-trapping properties. Experimental and theoretical analyses show that the vertically arranged channels in the SVG ensure rapid water transport and light trapping capabilities. The SVG achieves high freshwater production under 1 sun irradiation and can work in practical environments without performance degradation.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Multidisciplinary
Xianbo Wu, Mei Wen, Yuyan Zou, Xinyu Gao, Chuanwan Wei, Renyu Liu, Jianghua Li, Long Wang, Xilong Li, You-Nian Liu, Wansong Chen
Summary: Catalytic nanomedicine with the characteristics of catalysts brings unique properties to biomedicine. Cold-catalysts have been explored for antitumor therapy, showing potential for preventing tumor metastasis and recurrence through immunomodulation. This opens up exciting opportunities for the development of cold-catalytic nanomedicine.
Article
Pharmacology & Pharmacy
Renyu Liu, Jiangping Sheng, Ke Zeng, Yuanyuan Deng, Liu Deng, Lin Shen, You-Nian Liu
Summary: The study developed a biocompatible nanodrug platform, LZM@BP/MnO2 NSs, which showed enhanced efficacy of reactive oxygen species (ROS) against cancer cells in tumor therapy.
ADVANCED THERAPEUTICS
(2022)
Article
Chemistry, Inorganic & Nuclear
Caleb J. Bennett, Helen E. A. Brand, Alexander K. L. Yuen, Maria K. Nicholas, Brendan J. Kennedy
Summary: The temperature dependence of the crystal structure of Potassium Hexaiodoplatinate(IV) between 80 and 500 K is studied. Different crystal structures are observed at different temperatures, including monoclinic, tetragonal, and cubic structures. Accurate determination of the structures of K2PtI6 is important for further theoretical and practical research.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhuo Zeng, Jiangfu Zheng, Xiaoming Li, Changzheng Fan, Rongying Zeng, Wenqing Tang
Summary: An efficient method for phosphate removal from wastewater is urgently needed due to the environmental issue caused by excessive phosphorus. In this study, calcium aluminum layered double hydroxides (CaAl-LDHs) and six amino acid intercalated calcium aluminum layered double hydroxides (CaAl-amino acid-LDHs) were prepared and compared for their phosphate adsorption performance. L-Aspartic acid intercalated calcium aluminum layered double hydroxides (CaAl-Asp-LDHs) exhibited the highest phosphate adsorption capacity and faster removal rate compared to CaAl-LDHs. The phosphate adsorption mechanism on CaAl-Asp-LDHs involved electrostatic attraction, hydrogen bonds, complexation, and ion exchange. This environmentally friendly material shows promising potential for efficient phosphate removal from aquatic environments.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rouzbeh Aghaei Hakkak, Thomas Schleid
Summary: The novel guanidinium hydro-closo-borates with [BnHn]2- (n = 10 and 12) anions were successfully synthesized via direct reaction. The crystal structures exhibit hydrogen bonding interactions and have the potential to facilitate H2 generation.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liqiang Ma, Pengpeng Wei, Jingfang Li, Liye Liang, Guangming Li
Summary: A novel catalyst, H4PVMo2W9O40@rht-MOF-1, was developed using a one-pot hydrothermal method. It exhibited high efficiency and reusability in esterification reactions.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liudmila A. Gorelova, Valentiva A. Yukhno, Maria G. Krzhizhanovskaya, Oleg S. Vereshchagin
Summary: Two new Ga-Ge disordered feldspar-related compounds were successfully synthesized using melt crystallization methods. Their stability and thermal expansion properties were studied under high-temperature conditions. The results showed that both compounds are stable within the studied temperature range and exhibit anisotropic thermal expansion.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Seifeddine Bdey, Nesrine Boussadoune, Francois Allard, Jacques Huot, Gabriel Antonius, Noura Fakhar Bourguiba, Pedro Nunez
Summary: The structure of a novel arsenate compound Na3Al3(AsO4)4 has been determined using X-ray diffraction. The crystal exhibits a monoclinic space group with suitable pathways for Na+ ion migration. The accuracy of the structural model was confirmed using various validation tools and density functional theory calculations.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Amit Kumar Atri, Ujwal Manhas, Sumit Singh, Irfan Qadir, Shikha Sharma, Preteek Sharma, Devinder Singh
Summary: This study synthesizes new oxygen deficient triple layered Ruddlesden-Popper (RP) phases via sol-gel method and investigates the effects of Cr3+ doping on their structural, optical, magnetic, and photocatalytic properties. The experimental results demonstrate that Cr3+ doping alters the interactions and leads to excellent photocatalytic performance in some phases.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Dat Le Thanh, Amandine Guiet, Emmanuelle Suard, Romain Berthelot
Summary: In this study, FeNb11O29 powder samples were prepared using a microwave-assisted solid-state synthesis method for the first time. The samples obtained rapidly from submicrometric oxide precursors showed enhanced cycling performance, possibly due to the easier ionic diffusion occurring in the smaller particles.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Raimund Ziegler, Felix R. S. Purtscher, Thomas S. Hofer, Gunter Heymann, Hubert Huppertz
Summary: We have successfully synthesized a new tellurium borate crystal under high-pressure and high-temperature conditions. The crystal structure and theoretical calculations have been thoroughly discussed.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Subhendu Jana, Eric A. Gabilondo, Paul A. Maggard
Summary: This study reports the synthesis and characterization of two previously unknown multinary selenides, Ba8Hf2Se11(Se-2) and Ba9Hf3Se14(Se-2), which display unique structures and optoelectronic properties competitive with existing perovskite-type chalcogenides.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Fei Ruan, Chonggui Lei, Fenglong Zhang, Jinxiao Bao, Fen Zhou, Min Xie, Pengfei Xu, Jianquan Gao
Summary: Studying the diffusion properties of hydrogen is important for designing new proton conductors. In the past, the chemical diffusion coefficient of hydrogen in proton conductors was usually obtained through a manual calculation method, resulting in difficulty in controlling the calculation accuracy. To address this issue, a mathematical algorithm and C language computer program were developed to calculate the chemical diffusion coefficient based on Fick's second law and Romberg numerical integral. The algorithm showed high precision and powerful computing function, and has the potential to replace the manual calculation method in calculating the chemical diffusion coefficient for hydrogen in proton conductors.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Deepika Shanubhogue, Suraj Mangavati, Ashok Rao, Ru-Ting Tsao, Yung-Kang Kuo
Summary: In this study, the effect of Y doping at the Sn-site on the structural, electrical, and low-temperature thermoelectric properties of the Cu2SnSe3 system is investigated. Y-doped compounds Cu2Sn1-xYxSe3 show reduced electrical resistivity, enhanced power factor, and decreased thermal conductivity, resulting in higher ZT values.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Wei Hong, Min Qing, Xun He, Lei Wang, Yu Pu, Qiyu Li, Zhimin He, Qin Dong, Rong Li, Xinglong Gou
Summary: This study developed a simple method to prepare SnS2 nanosheets and assembled them with MXene to form SnS2/MXene. The composite material exhibited abundant active sites, superior electron/ion transfer kinetics, and a unique 2D interlayer structure, resulting in high specific capacity, outstanding rate capability, and excellent cycling stability, with potential applications in LIBs.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Heng-Yu Ruan, Xue-Qian Wu, Tian-Yu Zhang, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: Two isostructural metalorganic frameworks (MOFs), CTGU-36-Co and CTGU-36-Ni, were synthesized, and CTGU-36-Ni demonstrated high activity as a molecular electrocatalyst for the methanol oxidation reaction.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rachid Fakhreddine, Ali Ouasri, Abderrahim Aatiq
Summary: This paper reports the synthesis, structure, and spectroscopic studies of three novel metal orthophosphate salts. The structures of these compounds were refined using X-ray powder diffraction data. The infrared and Raman analysis revealed their symmetries and the UV-visible investigation determined their optical properties.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)