Article
Chemistry, Multidisciplinary
Anna-Lena Hansen, Reinhard K. Kremer, Eva M. Heppke, Martin Lerch, Wolfgang Bensch
Summary: Nanosized cubic thiospinel FeCr2S4 samples were synthesized through ball milling and temperature treatment to reveal magnetic behaviors at low temperatures and under external magnetic fields. The magnetic properties are primarily influenced by the annealing temperature, exhibiting distinct transitions into ferrimagnetic and orbital ordered states.
Review
Chemistry, Multidisciplinary
Nicholas F. Dummer, David J. Willock, Qian He, Mark J. Howard, Richard J. Lewis, Guodong Qi, Stuart H. Taylor, Jun Xu, Don Bethell, Christopher J. Kiely, Graham J. Hutchings
Summary: The direct transformation of methane to methanol at a larger scale remains challenging due to the low reactivity of methane. This review examines several promising routes to methanol and evaluates the performance targets necessary for process development. It provides critical perspectives on future operation and discusses the emergence of active heterogeneous catalysts and their reaction mechanisms.
Article
Chemistry, Physical
Maya Ibrahim, Madona Labaki, Anne Ponchel, Jean-Marc Giraudon, Olivier Gardoll, Jean-Francois Lamonier
Summary: This study prepared hydroxyapatite supported CuO catalysts with the addition of beta-cyclodextrin and found that beta-cyclodextrin had a significant impact on the reducibility and dispersion of active species. It was discovered that hydroxyl groups in beta-cyclodextrin could minimize the aggregation process of CuO nanoparticles during calcination. The CuO catalyst prepared from beta-cyclodextrin exhibited higher efficiency in the oxidation of toluene compared to the conventional catalyst.
Article
Materials Science, Ceramics
H. Jalili, B. Aslibeiki, A. Hajalilou, O. Musalu, L. P. Ferreira, M. M. Cruz
Summary: Recent studies have demonstrated the importance of the chemical composition and shape of magnetic nanoparticles in determining their properties. In this study, we synthesized cube-like nanoparticles and bimagnetic nanocomposites using an eco-friendly co-precipitation method. The nanocomposites exhibited good exchange-coupling interaction between the hard and soft magnetic phases, resulting in enhanced saturation magnetization. These materials showed promise for use in magnetic hyperthermia.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Monica Sorescu, Jordan Jubeck, Matthew Knauss, Alice Perrin, Michael McHenry
Summary: This study investigated the structural and magnetic properties of cobalt ferrite nanoparticles exposed to mechanochemical activation with and without graphene nanoparticles. It was found that the degree of inversion decreased with milling time and the canting angle was studied as a function of ball milling time for both sets of samples. The hysteresis loops exhibited a wasp-waist shape when recorded at 5 K in an applied magnetic field of 5 T, and the blocking temperature of the samples was determined using zero-field-cooling-field-cooling measurements.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2021)
Article
Engineering, Electrical & Electronic
Erika Dutkova, Maria Jesus Sayagues, Martin Fabian, Jaroslav Kovac, Jaroslav Kovat, Matej Balaz, Martin Stahorsky
Summary: This work presents a rapid one-step mechanochemical synthesis method to prepare nanocrystalline CuSbS2, demonstrating its promising crystal structure, stability, and optical properties for potential application as light absorbers in photovoltaics. The study also suggests a novel approach for the preparation of other ternary semiconductor nanomaterials.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Materials Science, Multidisciplinary
M. A. Gabal
Summary: The thermal decomposition and phase transformations of PbC2O4-FeC2O4.2H(2)O mixture were studied using various characterization techniques. The formation of different iron oxides at different calcination temperatures was observed, indicating a complex decomposition mechanism leading to the formation of ferrites.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Chemistry, Multidisciplinary
Vera Haagen, Jakob Iser, Markus Schoerner, Dennis Weber, Tanja Franken, Peter Wasserscheid, Patrick Schuehle
Summary: This contribution presents a new efficient two-stage production route for green methanol from biomass. The hydrogenolysis step is focused on and a materials solution is proposed to solve the problem of catalyst corrosion caused by the acidic mixture formed in the previous biomass oxidation step. Cu0.9Al2O4 spinel materials are found to be effective catalysts with lower corrosion compared to commercial catalysts such as CuO/Cr2O3.
Article
Chemistry, Physical
Jacopo De Bellis, Michael Felderhoff, Ferdi Schuth
Summary: In this study, it was demonstrated that mixing multiple metal sources through ball milling can result in supported alloyed nanoparticles, expanding the method's application to the synthesis of supported bimetallic catalysts. The prepared Au-Pd and Au-Cu nanoparticles supported on MgO or YSZ were characterized using powder X-ray diffraction and electron microscopy, and their catalytic performance in CO oxidation was investigated to understand the impact of the synthetic method on the final catalyst materials.
CHEMISTRY OF MATERIALS
(2021)
Article
Engineering, Chemical
Dandan Liu, Shengtai Hou, Yuan Shu, Jiahua Zhao, Li Wang, Pengfei Zhang
Summary: The mechanochemical method proposed in this study can fabricate porous copper molybdate with a high specific surface area, leading to improved catalytic performance compared to traditional methods. The obtained CuxMo1-xOy catalyst exhibited good performance in Knoevenagel condensation reactions.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Review
Chemistry, Multidisciplinary
Takuya Tsuzuki
Summary: This article reviews the mechanochemical synthesis of metal-oxide nanoparticles and their wide-ranging applications. Mechanical energy input reduces the need for solvents or heating in the synthesis process, making it a sustainable method.
COMMUNICATIONS CHEMISTRY
(2021)
Article
Chemistry, Analytical
Hyung Joon Kim, Sung Wook Hyun, So Hee Kim, Hyunkyung Choi
Summary: Mn-Zn ferrite nanoparticles for magnetic hyperthermia applications were synthesized using a high temperature thermal decomposition method, with a maximum saturation magnetization of 83.2 emu/g. The results suggest that these synthesized nanoparticles have potential applications in the field of magnetic hyperthermia.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Sibel Sogukkanli, Takahiko Moteki, Masaru Ogura
Summary: Direct conversion of methane into methanol over Cu-CHA zeolites was successfully demonstrated with high selectivity, avoiding the formation of unwanted C2 oxygenates. The one-pot synthesis approach using a Cu complex as a structure-directing agent showed higher methanol production rate compared to conventional ion-exchange method.
Article
Chemistry, Multidisciplinary
Quanlan Liao, Kai Su, Hesan Cai, Tianxiang Zhao, Fei Liu
Summary: This paper presents the mechanochemical synthesis of carbene copper complexes for catalytic hydrogenation of CO2 to formate with H2. The addition of triethoxysilane activator significantly improves the catalytic activity, leading to the highest TON value of 5720. Stoichiometric reactions are conducted to support the rationality of the proposed catalytic cycle for H2 cleavage and CO2 activation.
JOURNAL OF CO2 UTILIZATION
(2022)
Article
Chemistry, Physical
Mikalai A. Artsiusheuski, Jeroen A. van Bokhoven, Vitaly L. Sushkevich
Summary: The one-step valorization of natural gas is still a challenge, and converting methane to methanol via chemical looping over copper-containing zeolites seems to be a promising route. CuMFI is one of the earliest successful methods, but the structure of the active sites in CuMFI and the influence of copper loading and Si/Al ratio on the copper speciation are still not well understood. It has been found that the Cu/Al ratio determines the selectivity of methane conversion in CuMFI by controlling the structure of the active dicopper sites.
Article
Environmental Sciences
Silviya Boycheva, Denitza Zgureva, Hristina Lazarova, Margarita Popova
Summary: This study investigates the influence of calcium content in CFA on the properties of coal fly ash zeolites, as well as the carbon capture capacity of different types of zeolites. The development of efficient adsorbents from CFA with varying composition is expected to contribute to environmental benefits and the advancement of CO2 capture technologies in the context of the circular economy.
Article
Nanoscience & Nanotechnology
Tanya Tsoncheva, Consolato Rosmini, Mihail Mihaylov, Jiri Henych, Kristina Chakarova, Nikolay Velinov, Daniela Kovacheva, Zuzana Nemeckova, Martin Kormunda, Radostina Ivanova, Ivanka Spassova, Konstantin Hadjiivanov
Summary: In this study, the effects of the Fe/Ce ratio and the calcination temperature of cerium-iron oxides on Nickel-decorated mesoporous cerium-iron oxide composites were investigated. The research delves into the complex role of the FeCe support in the reaction mechanism.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Silviya Boycheva, Denitza Zgureva-Filipova, Cyril Popov, Hristina Lazarova, Margarita Popova
Summary: This study investigates the modification of coal fly ash zeolites (CFAZ) through microwave plasma surface treatment, which enhances their catalytic activity in total VOC oxidation. The results show that different treatment times and plasma agents have varying effects on the properties and structure of the samples, with CHF3 favoring catalytic activity and SF6 inhibiting it. The development of low-cost and efficient catalysts is crucial for conserving critical raw materials and utilizing coal ash resources.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
(2022)
Article
Polymer Science
Zornica Todorova, Ivanka Nikolova, Margarita Popova, Petar Grozdanov, Daniela Karashanova, Neli Koseva
Summary: In this study, two modification pathways were used to enrich the eggshell membrane surface with glucopyranosyl units, resulting in improved protein recognition and reduced bacterial adhesion. The modified membranes demonstrated distinct functional properties, making them promising for various applications in biotechnology and materials science.
POLYMER INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Oyundari Tumurbaatar, Hristina Lazarova, Margarita Popova, Violeta Mitova, Pavletta Shestakova, Neli Koseva
Summary: SBA-15 and MCM-48 mesoporous silicas were modified with functionalized (3-aminopropyl)triethoxysilane (APTES) using the post-synthesis method, introducing N- and P-containing groups to the pore surface. The structure of the newly synthesized modifiers and their grafting onto the porous matrix were confirmed by multinuclear NMR and FTIR spectroscopies. The modified silicas exhibited enhanced CO2 adsorption capacity compared to the initial material, with stable performance observed over three adsorption/desorption cycles.
Article
Chemistry, Physical
Consolato Rosmini, Tanya Tsoncheva, Daniela Kovatcheva, Nikolay Velinov, Hristo Kolev, Daniela Karashanova, Momtchil Dimitrov, Boyko Tsyntsarski, David Sebastian, Maria Jesus Lazaro
Summary: Ceria-iron oxide mesoporous materials were modified with Ni-Fe alloys and further transformed into ferrous carbides and metal alloys encapsulated within carbon nanofibers. The modified phases showed high electrochemical activity and low overpotential in the Oxygen Evolution Reaction. The morphological, textural and physicochemical properties of the samples were characterized in detail.
Article
Chemistry, Multidisciplinary
Nina Popov, Mira Ristic, Victor Kuncser, Kreso Zadro, Nikolay Velinov, Petre Badica, Andrei Alexandru-Dinu, Nicusor Iacob, Ljerka Kratofil Krehula, Svetozar Music, Stjepko Krehula
Summary: Substitution of Fe3+ by Er3+ in hematite resulted in changes in morphology and structure, affecting the magnetic and optical properties. This substitution caused a decrease in hyperfine magnetic field, coercive field, and Morin transition temperature, and an increase in magnetic susceptibility and narrowing of the optical band gap.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2022)
Article
Biochemistry & Molecular Biology
Margarita Popova, Ivalina Trendafilova, Manuela Oykova, Yavor Mitrev, Pavleta Shestakova, Magdolna R. Mihalyi, Agnes Szegedi
Summary: Monometallic and bimetallic catalysts supported on KIT-6 based mesoporous silica/zeolite composites were prepared and characterized. The bimetallic CuNi-KIT-6 catalyst showed high stability and conversion rate in gas-phase reactions.
Article
Chemistry, Multidisciplinary
Ivalina Trendafilova, Ralitsa Chimshirova, Denitsa Momekova, Hristo Petkov, Neli Koseva, Penka Petrova, Margarita Popova
Summary: Biologically active substances of natural origin are a promising alternative for treating skin diseases. The limitations of low water solubility and bioavailability in natural compounds can be overcome by developing suitable delivery systems. In this study, a silver-modified mesoporous silica nanocarrier was prepared using the template exchange procedure. The drug-loaded formulation showed high loading efficiency, and the interaction between drugs and carriers was studied. The release experiments demonstrated improved solubility, and the formulations exhibited potent antiradical, antioxidant, and antibacterial activities. The simultaneous delivery of curcumin and capsaicin showed enhanced antiproliferative effects on maligning cells. These findings suggest that the developed delivery systems have promising potential for dermal treatment.
Article
Biochemistry & Molecular Biology
Ivalina Trendafilova, Manuel Ojeda, John M. Andresen, Alenka Ristic, Momtchil Dimitrov, Natasa Novak Tusar, Genoveva Atanasova, Margarita Popova
Summary: Transition metals as catalysts for total VOC oxidation at low temperatures are challenging. This study prepared and tested iron-modified SBA-15, AlSBA-15, and ZrSBA-15 materials with varying Fe loading for toluene oxidation. The results showed that increasing Fe loading improved the oxidation rate and decreased the temperature required for complete toluene removal. Surface properties of the mesoporous support influenced the type and localization of iron oxide species, and 5 wt. % Fe-containing ZrSBA-15 exhibited excellent activity in the total oxidation of toluene at lower temperatures due to the synergistic effect of Fe-Zr and the presence of accessible and stable Fe2+/Fe3+ active sites.
Article
Chemistry, Physical
Margarita Popova, Manuela Oykova, Momtchil Dimitrov, Daniela Karashanova, Daniela Kovacheva, Genoveva Atanasova, Agnes Szegedi
Summary: Mono- and bimetallic Ni- and Ru-modified micro-mesoporous ZSM-5 catalysts were prepared and their physicochemical properties were studied. The results showed that the zeolite structure and modification procedure influenced the formation, dispersion, and reducibility of metal oxides. Nickel dispersion was higher and more reducible in the presence of ruthenium in bimetallic catalysts. In CO2 hydrogenation to methane, 10Ni5RuZSM-5 material exhibited the highest activity and selectivity.
Article
Chemistry, Multidisciplinary
Vencislav Tumbalev, Daniela Kovacheva, Ivanka Spassova, Ralitsa Velinova, Georgi Tyuliev, Nikolay Velinov, Anton Naydenov
Summary: This study reports on MnCoFeO4 spinels with peculiar composition and their catalytic behavior in the reactions of complete oxidation of hydrocarbons. The spinel prepared with sucrose as the fuel shows higher catalytic activity, possibly due to its higher specific surface area, pore volume, and thermal stability.
Article
Chemistry, Multidisciplinary
Mia Stankovic, Margarita Popova, Matjaz Mazaj, Goran Drazic, Andraz Suligoj, Nigel van de Velde, Mojca Opresnik, Zeljko Jacimovic, Natasa Novak Tusar, Natasa Zabukovec Logar
Summary: This study reveals the potential of waste metal-loaded zeolite generated through wastewater treatment as an effective catalyst for removing volatile organic compounds (VOCs) from air. The thermally treated natural zeolite Clinoptilolite showed good catalytic performance in toluene oxidation and cycling stability.
FRONTIERS IN CHEMISTRY
(2022)
Article
Chemistry, Applied
Silviya Boycheva, Agnes Szegedi, Karoly Lazar, Cyril Popov, Margarita Popova
Summary: The coal fly ash zeolites with increased iron oxide content were prepared and modified using radiofrequency plasma treatment. The plasma-modified iron-enriched zeolite showed high catalytic activity for VOC oxidation. The CO2 adsorption capacity of the plasma-modified zeolite under dynamic conditions was also investigated.
Article
Chemistry, Analytical
Silviya Boycheva, Kristina Chakarova, Mihail Mihaylov, Konstantin Hadjiivanov, Margarita Popova
Summary: This study found that calcium has a positive effect on the carbon capture capacity of coal fly ash zeolites, increasing their adsorption capacity. It raises an important question regarding coal ash classification for the synthesis of zeolites with carbon capture applications.
ENVIRONMENTAL SCIENCE-PROCESSES & IMPACTS
(2022)
Article
Chemistry, Inorganic & Nuclear
Caleb J. Bennett, Helen E. A. Brand, Alexander K. L. Yuen, Maria K. Nicholas, Brendan J. Kennedy
Summary: The temperature dependence of the crystal structure of Potassium Hexaiodoplatinate(IV) between 80 and 500 K is studied. Different crystal structures are observed at different temperatures, including monoclinic, tetragonal, and cubic structures. Accurate determination of the structures of K2PtI6 is important for further theoretical and practical research.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhuo Zeng, Jiangfu Zheng, Xiaoming Li, Changzheng Fan, Rongying Zeng, Wenqing Tang
Summary: An efficient method for phosphate removal from wastewater is urgently needed due to the environmental issue caused by excessive phosphorus. In this study, calcium aluminum layered double hydroxides (CaAl-LDHs) and six amino acid intercalated calcium aluminum layered double hydroxides (CaAl-amino acid-LDHs) were prepared and compared for their phosphate adsorption performance. L-Aspartic acid intercalated calcium aluminum layered double hydroxides (CaAl-Asp-LDHs) exhibited the highest phosphate adsorption capacity and faster removal rate compared to CaAl-LDHs. The phosphate adsorption mechanism on CaAl-Asp-LDHs involved electrostatic attraction, hydrogen bonds, complexation, and ion exchange. This environmentally friendly material shows promising potential for efficient phosphate removal from aquatic environments.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rouzbeh Aghaei Hakkak, Thomas Schleid
Summary: The novel guanidinium hydro-closo-borates with [BnHn]2- (n = 10 and 12) anions were successfully synthesized via direct reaction. The crystal structures exhibit hydrogen bonding interactions and have the potential to facilitate H2 generation.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liqiang Ma, Pengpeng Wei, Jingfang Li, Liye Liang, Guangming Li
Summary: A novel catalyst, H4PVMo2W9O40@rht-MOF-1, was developed using a one-pot hydrothermal method. It exhibited high efficiency and reusability in esterification reactions.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liudmila A. Gorelova, Valentiva A. Yukhno, Maria G. Krzhizhanovskaya, Oleg S. Vereshchagin
Summary: Two new Ga-Ge disordered feldspar-related compounds were successfully synthesized using melt crystallization methods. Their stability and thermal expansion properties were studied under high-temperature conditions. The results showed that both compounds are stable within the studied temperature range and exhibit anisotropic thermal expansion.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Seifeddine Bdey, Nesrine Boussadoune, Francois Allard, Jacques Huot, Gabriel Antonius, Noura Fakhar Bourguiba, Pedro Nunez
Summary: The structure of a novel arsenate compound Na3Al3(AsO4)4 has been determined using X-ray diffraction. The crystal exhibits a monoclinic space group with suitable pathways for Na+ ion migration. The accuracy of the structural model was confirmed using various validation tools and density functional theory calculations.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Amit Kumar Atri, Ujwal Manhas, Sumit Singh, Irfan Qadir, Shikha Sharma, Preteek Sharma, Devinder Singh
Summary: This study synthesizes new oxygen deficient triple layered Ruddlesden-Popper (RP) phases via sol-gel method and investigates the effects of Cr3+ doping on their structural, optical, magnetic, and photocatalytic properties. The experimental results demonstrate that Cr3+ doping alters the interactions and leads to excellent photocatalytic performance in some phases.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Dat Le Thanh, Amandine Guiet, Emmanuelle Suard, Romain Berthelot
Summary: In this study, FeNb11O29 powder samples were prepared using a microwave-assisted solid-state synthesis method for the first time. The samples obtained rapidly from submicrometric oxide precursors showed enhanced cycling performance, possibly due to the easier ionic diffusion occurring in the smaller particles.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Raimund Ziegler, Felix R. S. Purtscher, Thomas S. Hofer, Gunter Heymann, Hubert Huppertz
Summary: We have successfully synthesized a new tellurium borate crystal under high-pressure and high-temperature conditions. The crystal structure and theoretical calculations have been thoroughly discussed.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Subhendu Jana, Eric A. Gabilondo, Paul A. Maggard
Summary: This study reports the synthesis and characterization of two previously unknown multinary selenides, Ba8Hf2Se11(Se-2) and Ba9Hf3Se14(Se-2), which display unique structures and optoelectronic properties competitive with existing perovskite-type chalcogenides.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Fei Ruan, Chonggui Lei, Fenglong Zhang, Jinxiao Bao, Fen Zhou, Min Xie, Pengfei Xu, Jianquan Gao
Summary: Studying the diffusion properties of hydrogen is important for designing new proton conductors. In the past, the chemical diffusion coefficient of hydrogen in proton conductors was usually obtained through a manual calculation method, resulting in difficulty in controlling the calculation accuracy. To address this issue, a mathematical algorithm and C language computer program were developed to calculate the chemical diffusion coefficient based on Fick's second law and Romberg numerical integral. The algorithm showed high precision and powerful computing function, and has the potential to replace the manual calculation method in calculating the chemical diffusion coefficient for hydrogen in proton conductors.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Deepika Shanubhogue, Suraj Mangavati, Ashok Rao, Ru-Ting Tsao, Yung-Kang Kuo
Summary: In this study, the effect of Y doping at the Sn-site on the structural, electrical, and low-temperature thermoelectric properties of the Cu2SnSe3 system is investigated. Y-doped compounds Cu2Sn1-xYxSe3 show reduced electrical resistivity, enhanced power factor, and decreased thermal conductivity, resulting in higher ZT values.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Wei Hong, Min Qing, Xun He, Lei Wang, Yu Pu, Qiyu Li, Zhimin He, Qin Dong, Rong Li, Xinglong Gou
Summary: This study developed a simple method to prepare SnS2 nanosheets and assembled them with MXene to form SnS2/MXene. The composite material exhibited abundant active sites, superior electron/ion transfer kinetics, and a unique 2D interlayer structure, resulting in high specific capacity, outstanding rate capability, and excellent cycling stability, with potential applications in LIBs.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Heng-Yu Ruan, Xue-Qian Wu, Tian-Yu Zhang, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: Two isostructural metalorganic frameworks (MOFs), CTGU-36-Co and CTGU-36-Ni, were synthesized, and CTGU-36-Ni demonstrated high activity as a molecular electrocatalyst for the methanol oxidation reaction.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rachid Fakhreddine, Ali Ouasri, Abderrahim Aatiq
Summary: This paper reports the synthesis, structure, and spectroscopic studies of three novel metal orthophosphate salts. The structures of these compounds were refined using X-ray powder diffraction data. The infrared and Raman analysis revealed their symmetries and the UV-visible investigation determined their optical properties.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
