期刊
JOURNAL OF RARE EARTHS
卷 28, 期 3, 页码 435-438出版社
ELSEVIER
DOI: 10.1016/S1002-0721(09)60128-9
关键词
lithium-ion batteries; impedance; conductivity; dielectric analysis; complex modulus; rare earths
LiCeO2 was prepared by a solid-state reaction method using microwave heat treatment and identified by X-ray diffractometry. LiCeO2 has monoclinic crystal structure whose conductivity and dielectric properties were studied over a range of frequency (42 Hz to 1 MHz) and temperatures (30-500 degrees C) using ac technique of complex impedance analyzer HIOKI 3532. Combined impedance and modulus plots were used as tools to analyze the sample behaviour as a function of frequency at different temperatures. The d.c. conductivity (sigma(dc)) followed the Arrhenius relation. The modulus analysis and dielectrics studies showed the non-Debye dielectric relaxation nature.
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