4.7 Article Proceedings Paper

New cadmium and rare earth metal tungstates with the scheelite type structure

期刊

JOURNAL OF RARE EARTHS
卷 27, 期 4, 页码 569-573

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ELSEVIER SCIENCE BV
DOI: 10.1016/S1002-0721(08)60290-2

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rare earth metal tungstates; scheelite type structure; XRD; DTA-TG; EPR

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New cadmium and rare earth metal tungstates with the formula Cd0.25RE0.50 square 0.25WO4 (RE=Nd, Sm, Eu, Gd, square-statisfical distributed vacancies in cation sublattice) were synthesized by the solid-state reaction between CdWO4 and corresponding RE2W2O9. The obtained phases crystallize in the scheelite type structure. The Cd0.25RE0.50 square 0.25WO4 compounds were characterized by X-ray diffractometer (XRD), (DTA-TG), infrared (IR) and EPR methods.

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