期刊
JOURNAL OF RAMAN SPECTROSCOPY
卷 43, 期 6, 页码 689-691出版社
WILEY-BLACKWELL
DOI: 10.1002/jrs.3098
关键词
porphyrin; TMPyP; detection
类别
资金
- Operational Program Research and Development for Innovations - European Regional Development Fund of the Ministry of Education, Youth and Sports of the Czech Republic [CZ.1.05/2.1.00/03.0058]
- GACR [P108/11/P657]
Surface-enhanced resonance Raman scattering (SERRS) spectroscopy is a powerful tool for the selective and sensitive detection of porphyrins. We report a repeatable detection of unperturbed free base 5,10,15,20-tetrakis(1-methyl-4-pyridyl)21H,23H-porphine in concentrations as low as 1 x 10(13)?M in the final system when Ag nanoparticles prepared by modified Tollens method are employed as Raman scattering amplifiers, i.e. without any further post-modifications of their surface. Most probably the residues of sugar oxidation present on Ag nanoparticle surface are responsible for the effective protection of 5,10,15,20-tetrakis(1-methyl-4-pyridyl)21H,23H-porphine molecules against the metalation by silver. Copyright (C) 2011 John Wiley & Sons, Ltd.
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