期刊
JOURNAL OF RAMAN SPECTROSCOPY
卷 41, 期 1, 页码 12-15出版社
WILEY-BLACKWELL
DOI: 10.1002/jrs.2398
关键词
SERS; silver; colloids; extraterrestrial investigations
类别
资金
- Italian Ministero dell'Universita e Ricerca (MIUR)
- University of Firenze (Italy)
SERS spectroscopy with 785-nm laser excitation minimizing fluorescence emission is exploited for remote analysis of life traces in an extraterrestrial environment. Adenine and guanine, nucleobases present in both DNA and RNA strands, and microRNA containing adenine and guanine have been used as testing ligands for identifying traces of nucleic acids in Martian rocks and sediments. SERS spectra of these nucleobase samples adsorbed on pyroxene substrates have been investigated with micro-Raman apparatus in the absence of sample manipulation and inducing the signal enhancement by deposition of silver colloidal nanoparticles over the pyroxene/nucleobase substrates. An order-of-magnitude estimate of the sample amount responsible for the SERS spectra is given. Copyright (C) 2009 John Wiley & Sons, Ltd.
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