期刊
JOURNAL OF RAMAN SPECTROSCOPY
卷 40, 期 9, 页码 1093-1095出版社
JOHN WILEY & SONS LTD
DOI: 10.1002/jrs.2390
关键词
Raman optical activity; Fmoc-dipeptides; self-assembly; chirality; nanomaterial
类别
资金
- EPSRC [EP/D033764/1, GR/s75727/01]
- Engineering and Physical Sciences Research Council [GR/S75727/01] Funding Source: researchfish
Raman optical activity (ROA) is a relatively new technique used to determine the structure of chiral molecules and is proving useful in the study of biological molecules such as proteins and DNA/RNA. Here, for the first time, we demonstrate the applicability of ROA as a technique to study achiral groups in chiral environments, detecting the induced chiralty of N-(fluorenyl-9-methoxycarbonyl) (Fmoc) in a chiral self-assembled structure of Fmoc-dipeptides. This technique is therefore of interest to those studying self-assembled systems that adopt a chiral structure. Copyright (C) 2009 John Wiley & Sons, Ltd.
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