Article
Chemistry, Multidisciplinary
Shuang Zhou, Zhong Wang, Chenyu Dong, Jie Bian, Weihua Zhang
Summary: This study investigated the wavelength-dependent laser-induced dynamic annealing of single plasmonic nano-antennas using in situ white light spectroscopy. The experiment revealed unexpected back-and-forth motions of rapidly melted single nano-antennas under excitation with a 532 nm laser, while gradual opening of nanogaps was observed with a 405 nm laser. Theoretical analyses suggested that the complex dynamics were caused by multiphysical processes at the nanoscale induced by the laser.
Article
Thermodynamics
M. J. Dunn, A. R. W. Macfarlane, R. S. Barlow, D. Geyer, K. Dieter, A. R. Masri
Summary: This study presents new measurements of species concentrations, temperature and mixture fraction in turbulent ethanol spray flames. The use of appropriate flame conditions, high sensitivity Raman detection system, and a pre-processing algorithm contributed to successful measurement of flame parameters.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2021)
Article
Chemistry, Multidisciplinary
Richard Murray, Micheal Burke, Daniela Iacopino, Aidan J. Quinn
Summary: This study demonstrates a scalable method for in situ fabrication of high-quality graphene-like materials using a CO2 laser engraver. An iterative optimization strategy was developed to identify promising parameter combinations, highlighting the benefits of rapid identification of optimum parameters for graphene electrode fabrication. The study shows that the laser graphitization process is highly non-linear, emphasizing the importance of efficient optimization methods for achieving high-quality graphene-based sensors and electronic devices.
Article
Optics
Cihang Kong, Christian Pilger, Manuel Kunisch, Christine Foerster, Jan Schulte am Esch, Thomas Huser
Summary: Coherent Raman scattering (CRS) microscopy is a label-free imaging method with high chemical sensitivity and sub-micron spatial resolution. A tunable two-color fiber laser with superior noise performance is demonstrated. Large-area multimodal imaging of human liver tissue sections is achieved and compared to commercial laser data.
LASER & PHOTONICS REVIEWS
(2023)
Article
Chemistry, Physical
Adam G. Knight, Carlota Sieira Olivares, Maksymilian J. Roman, Daniel R. Moon, Paul D. Lane, Matthew L. Costen, Kenneth G. McKendrick
Summary: The effects of experimental parameter spreads on the reliability of speeds and angular distributions in a surface-scattering experiment were analyzed. A numerical model involving a pulsed beam of molecules impacting a surface and detecting the scattered products through laser-induced fluorescence was used. Monte Carlo sampling was employed to select realistic experimental parameters. The molecular-beam diameter to measurement distance ratio was identified as a crucial parameter, with negligibly distorted angular distributions observed at smaller ratios.
JOURNAL OF CHEMICAL PHYSICS
(2023)
Article
Chemistry, Analytical
Zhifeng Zhu, Xiaoyu Wang, Tengfei Wu, Zhongshan Li, Ercong Gao, Qiang Gao, Bo Li
Summary: This study investigated the effect of gas temperature on LIBS measurements and found that temperature variations can affect the accuracy of LIBS measurements. By using a large gate width and a suitable delay time, the impact of gas temperature can be reduced.
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2023)
Article
Optics
Davide Gatti, Marco Lamperti, Attilio Zilli, Francesco Canella, Giulio Cerullo, Gianluca Galzerano, Paolo Laporta, Nicola Coluccelli
Summary: A laser system is introduced for standoff coherent anti-Stokes Raman scattering (CARS) spectroscopy under ambient light conditions. The system allows for high-resolution Raman spectra and hyperspectral imaging.
Article
Optics
Lei Han, Qiang Gao, Bo Li, Ming Li, Dayuan Zhang, Xuesong Bai, Zhongshan Li
Summary: This study presents a method for simultaneously measuring velocity and concentration using femtosecond laser-induced chemiluminescence. By measuring the decay of CN radical fluorescence and using two-dimensional imaging, the simultaneous measurement of velocity and mixture fraction can be achieved.
OPTICS AND LASERS IN ENGINEERING
(2022)
Article
Optics
Fabing Li, Ying Wang, Haiying Zhao, Xin Xu, Cunming Liu, Zhiwei Men, Chenglin Sun
Summary: This study indirectly determined the effective pressure caused by LIB in liquid pure H2O and low concentration H2O-H2O2 mixtures using Raman spectroscopy, and derived an empirical equation to estimate the LIB effective pressures for other different mixture water solutions. The method provides a way to advance the measurements of effective pressure in the LIB process.
Article
Chemistry, Multidisciplinary
Sudeshna Chattopadhyay, Vikas Munya, Ravinder Kumar, Dipayan Pal, Sucheta Bandyopadhyay, Arpan Ghosh, Priyanka Yogi, Julian Koch, Herbert Pfnur
Summary: The study of surface-modified system F4-TCNQ/EG/SiC using X-ray photoelectron spectroscopy (XPS) and angle-resolved polarized Raman spectroscopy (ARPRS) showed that the bonding of deposited F4-TCNQ molecules depends on their concentration. Charge transfer from graphene to fluorine is evident only at sub-monolayer concentrations, with a corresponding change in bond character coupled with a change in molecular orientation. Raman spectroscopy also revealed a significant degree of molecular stacking above the monolayer concentration.
Article
Engineering, Electrical & Electronic
Shengtao Lin, Zinan Wang, Yifei Qi, Bing Han, Han Wu, Yunjiang Rao
Summary: Interrogating a remote passive-sensor with high fidelity is a major challenge in the sensing domain. This study proposes a novel dynamic sensing scheme based on a backward-pumped random fiber laser, and investigates its sensing bandwidth theoretically and experimentally. The results demonstrate that this scheme enables ultra-high-bandwidth and ultra-long-distance interrogation for optical fiber sensors.
JOURNAL OF LIGHTWAVE TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
K. A. Smith, S. P. Ramkumar, N. C. Harms, A. J. Clune, S-W Cheong, Z. Liu, E. A. Nowadnick, J. L. Musfeldt
Summary: This study investigated the pressure-driven phase transition in multiferroic h-Lu0.6Sc0.4FeO3 using a combination of techniques, including diamond anvil cell techniques, synchrotron-based infrared and Raman scattering spectroscopies, symmetry analysis, and lattice dynamics calculations. The comparison of measured and predicted phonon patterns revealed a structural transition at 15 GPa. The symmetry breaking across the polar -> antipolar transition was found to be analogous to other materials with strain-driven and temperature-induced transitions.
Article
Chemistry, Multidisciplinary
Lei Ouyang, Tobias Meyer-Zedler, Kel-Meng See, Wei-Liang Chen, Fan-Cheng Lin, Denis Akimov, Sadaf Ehtesabi, Martin Richter, Michael Schmitt, Yu-Ming Chang, Stefanie Grafe, Jurgen Popp, Jer-Shing Huang
Summary: This study investigates the enhancement effect of plasmonic gratings in nonlinear surface-enhanced coherent anti-Stokes Raman scattering (SECARS) using the platform of plasmonic Doppler grating (PDG). The PDGs spatially separate the input and output enhancement, allowing for observation and comparison of overall enhancement from different combinations of individual input and output beams. The results indicate that enhancement in the pump and anti-Stokes beams plays a more critical role in the overall enhancement than that in the Stokes beam.
Article
Physics, Applied
Li Wang, Tsung-Tse Lin, Ke Wang, Hideki Hirayama
Summary: This study investigates the impact of parasitic absorption in the narrow module architecture with only two quantum wells, in the context of terahertz quantum cascade lasers utilizing the nonalignment injection scheme via direct-phonon resonance. The optical gain is found to be limited to small (or negative) values even at low temperatures. To address this issue, a strategy of suppressing parasitic absorption by increasing the injection energy is adopted, resulting in successful lasing at 194 K.
APPLIED PHYSICS LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Jun Kikkawa, Koji Kimoto
Summary: In this study, a method for temperature measurement using monochromated electron probes is reported. Based on the principle of balancing between the annihilation and creation of phonons, this method enables the investigation of local static and dynamic thermal properties in various materials and devices. The use of acoustic phonons improves the accuracy of low-temperature measurements.
Article
Thermodynamics
Malte F. B. Stodt, Chenyang Liu, Shuiqing Li, Lutz Maedler, Udo Fritsching, Johannes Kiefer
Summary: This study investigates the flame spray pyrolysis of iron oxide nanoparticles using the new reference nozzle SpraySyn and applies the PS-LIBS technique to study particle formation under different precursor solutions. Significant differences in atomic emission spectra are observed when adding 2-ethylhexanoic acid to precursors, enabling differentiation between different particle formation routes. The experimental results provide deep insights into combustion and particle nucleation kinetics in spray flames, with potential applications for numerical simulations.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2021)
Article
Optics
Joseph D. Miller, Johannes W. Troeger, Sascha R. Engel, Thomas Seeger, Alfred Leipertz, Terrence R. Meyer
Summary: An optical parametric oscillator (OPO) is developed for simultaneous UV and near-UV laser imaging in turbulent flames, enabling identification and quantification of high-temperature flame layers and combustion product zones. Considerations for future high-speed acquisition are discussed.
Article
Energy & Fuels
Anna Ballhause, Sabine Wagenfeld, Johannes Kiefer, Wolffram Schroeer, Bernd Rathke
Summary: This study systematically investigates the liquid-liquid phase behavior of ternary mixtures of n-hexadecane, its isomer 2,2,4,4,6,8,8-heptamethylnonane, and ethanol as a model system. The binary mixtures show partial miscibility with upper critical solution points, with the behavior of the ternary mixtures examined through quasi-binary subsystems. By changing the mole ratios of the isomers, the phase diagram shifts gradually, allowing for a comprehensive description of the liquid-liquid phase behavior.
Article
Optics
Henry Misoi, Jonas Hoelzer, Thomas Seeger
Summary: This paper investigates the temperature dependence of the O-2 and CO2 S-branch linewidths in a 30/70% O-2 - CO2 mixture using a picosecond time-resolved pure rotational coherent anti-Stokes Raman scattering (RCARS) approach. The obtained linewidths show significant deviations from pure self-broadened linewidths and previously used Q-branch linewidths. Discussions are also provided on the implications for RCARS thermometry and concentration evaluations.
Editorial Material
Optics
Frank Beyrau, Joakim Bood, Paul Hsu, Johannes Kiefer, Thomas Seeger, Hans Stauffer
Summary: This feature issue focuses on the application of lasers in chemical, security, and environmental analysis, highlighting papers presented at the LACSEA 2020 Seventeenth Topical Meeting sponsored by The Optical Society (OSA).
Article
Energy & Fuels
Christian Meissner, Henrik Schneider, Evaggelos Sidiropoulos, Jonas Hoelzer, Tim Heckmann, Benjamin Boehm, Andreas Dreizler, Thomas Seeger
Summary: This study focused on the wall and gas phase temperatures inside a swirled oxy-fuel combustion chamber, comparing different methods such as vibrational CARS and rotational CARS for gas phase temperature measurements. The developed O-2-VCARS system was successfully tested in a harsh environment to provide a measurement tool for gas-assisted pulverized solid fuel flames, with discussions on possible error sources related to particles within the probe volume.
Article
Spectroscopy
Johannes Kiefer, Malte F. B. Stodt, Udo Fritsching
Summary: This study proposes and demonstrates two straightforward approaches to identify spatial averaging and estimate the resulting error. By considering simulated Raman spectra, it is shown that the resulting measurement error can be as high as 500 K.
JOURNAL OF RAMAN SPECTROSCOPY
(2021)
Article
Engineering, Chemical
M. Ulrich Goebel, Juergen U. Keller, Karl Meller, Ingo Schmitz, Thomas Seeger, Eva Schieferstein
Summary: By measuring the adsorption and desorption behavior of activated carbon filters on fuel vapor mixtures over time, it was found that dry regeneration can enhance their long-term suitability. This study helps explain the increased filter failures due to bioethanol blends and moist regeneration fluid.
CHEMIE INGENIEUR TECHNIK
(2022)
Article
Engineering, Chemical
Manfred Ulrich Goebel, Juergen U. Keller, Karl Meller, Ingo Schmitz, Thomas Seeger, Eva Schieferstein
Summary: This paper discusses the importance of fuel vapor retaining systems in gasoline vehicles and presents measurements of the regeneration processes using high humidity gas. It also highlights the limitations of current testing procedures and quality parameters in representing real operating conditions, and suggests the need for new standards.
Article
Thermodynamics
M. F. B. Stodt, Jan Derk Groeneveld, Lutz Maedler, Johannes Kiefer, Udo Fritsching
Summary: This study investigates the occurrence of in-flight droplet microexplosions (mu-explosions) during flame spray pyrolysis and confirms the findings through single drop experiments. It is found that there are distinct mu-explosions happening at high frequencies during the synthesis of iron oxide nanoparticles. This finding is significant for understanding the role and relevance of mu-explosions in the production and formulation of functional nanoparticles.
COMBUSTION AND FLAME
(2022)
Article
Mechanics
E. V. Barmina, M. I. Zhilnikova, K. O. Aiyyzhy, V. D. Kobtsev, D. N. Kozlov, S. A. Kostritsa, S. N. Orlov, A. M. Saveliev, V. V. Smirnov, N. S. Titova, G. A. Shafeev
Summary: In this study, the temperature distribution in the diffusion flame during the combustion of isopropanol or isopropanol with the addition of boron nanoparticles was experimentally studied using CARS spectroscopy. The results showed that the addition of boron resulted in a temperature increase of 150 K in the flame front.
Article
Chemistry, Physical
Joerg Lampe, Steffen Menz, Kander Akinci, Kai Boehm, Thomas Seeger, Thomas Fend
Summary: This paper investigates the operational strategy of a pilot plant for regenerative hydrogen production based on two-step thermochemical redox cycles, with a focus on optimizing operational parameters for the highest solar-to-fuel efficiency. Using a highly accurate simulation model and well-suited optimization routines, new insights into the most efficient operational strategies are revealed. The study considers the material and technical limits of the used components, yielding reliable practical results. Optimal operational parameters are found using a temperature swing strategy, resulting in a solar-to-fuel plant efficiency of up to 1.1%.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Green & Sustainable Science & Technology
Steffen Menz, Joerg Lampe, Johann Krause, Thomas Seeger, Thomas Fend
Summary: In this study, a comprehensive energy flow analysis of a solar driven pilot plant for green hydrogen production is conducted. The analysis quantifies energy flows using a complex simulation model and examines the impact of plant design, operational strategy, and control parameters on plant efficiency. The study reveals the influence of a heat recovery system and heat losses on system efficiency, identifies potential efficiency improvements, and discusses possibilities for plant design and material modifications.
Article
Thermodynamics
Johannes Emmert, Henrik Schneider, Christian Meissner, Evaggelos Sidiropoulos, Jonas I. Hoelzer, Thomas Seeger, Benjamin Boehm, Andreas Dreizler, Steven Wagner
Summary: Oxy-fuel combustion shows promise for efficient and cost-effective CO2 sequestration, but faces challenges in applying mature temperature measurement methods like CARS due to a lack of suitable diatomic species. This study demonstrates the use of linear hyperspectral absorption tomography on water vapor in an oxy-fuel coal combustor, providing complementary data to supplement other diagnostic methods. The results align quantitatively with vibrational O2-CARS measurements and qualitatively recreate spatial structures observed in particle image velocimetry flow fields.
APPLICATIONS IN ENERGY AND COMBUSTION SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
V. Yu Shishkov, E. S. Andrianov, A. A. Pukhov, A. P. Vinogradov, S. N. Orlov, Yu N. Polivanov, V. Fabelinsky, D. N. Kozlov, V. V. Smirnov, A. A. Lisyansky
Summary: This paper presents a theory that explains the experimentally observed features of photoluminescence spectrum in surface-enhanced Raman-scattering experiments from a unified perspective, covering the entire frequency range of the background. The theory suggests that photoluminescence is caused by cascade Brillouin scattering of the incident wave by metal phonons under plasmon resonance conditions, and it agrees well with measurements.