4.5 Article

Biosorption characteristics of uranium(VI) from aqueous solution by pummelo peel

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出版社

SPRINGER
DOI: 10.1007/s10967-012-1720-3

关键词

Pummelo peel; Biosorption; Uranium

资金

  1. National Natural Science Foundation of China [21101024]
  2. Chinese Ministry of Education [211086]
  3. Natural Science Foundation of Jiangxi Province [20114BAB203002, 2010GQH0015]
  4. China Postdoctoral Science Foundation [20110490857]
  5. Jiangxi Provincial Department of Education [GJJ11139]
  6. Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, China [2010RGET08]

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The biomass pummelo peel was chosen as a biosorbent for removal of uranium(VI) from aqueous solution. The feasibility of adsorption of U(VI) by Pummelo peel was studied with batch adsorption experiments. The effects of contact time, biosorbent dosage and pH on adsorption capacity were investigated in detail. The pummelo peel exhibited the highest U(VI) sorption capacity 270.71 mg/g at an initial pH of 5.5, concentration of 50 mu g/mL, temperature 303 K and contacting time 7 h. The adsorption process of U(VI) was found to follow the pseudo-second-order kinetic equation. The adsorption isotherm study indicated that it followed both the Langmuir adsorption isotherm and the Freundlich adsorption isotherm. The thermodynamic parameters values calculated clearly indicated that the adsorption process was feasible, spontaneous and endothermic in nature. These properties show that the pummelo peel has potential application in the removal of the uranium(VI) from the radioactive waste water.

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