4.8 Article

One-pot synthesis of monodisperse palladium-copper nanocrystals supported on reduced graphene oxide nanosheets with improved catalytic activity and methanol tolerance for oxygen reduction reaction

期刊

JOURNAL OF POWER SOURCES
卷 269, 期 -, 页码 104-110

出版社

ELSEVIER
DOI: 10.1016/j.jpowsour.2014.07.036

关键词

Bimetallic nanocrystals; Reduced graphene oxide; Oxygen reduction reaction; Methanol tolerance

资金

  1. NSFC [21175118, 21275130, 21275131, 11304286]
  2. Zhejiang Province University young academic leaders of academic climbing project [pd2013055]

向作者/读者索取更多资源

Monodisperse bimetallic alloyed palladium copper nanocrystals are uniformly supported on reduced graphene oxide nanosheets by a one-pot solvothermal strategy, with an average size of 6.81 nm. As a result, the as-prepared nanocomposites have the enlarged electrochemically active surface area (49.2 m(2) g(-1)), and display the improved electrocatalytic performance and high methanol-tolerance ability for oxygen reduction reaction in alkaline media, compared with commercial Pd black and RGOs. Those RGOs-supporting Pd-Cu alloys would have potential applications in fuel cells. (C) 2014 Elsevier B.V. All rights reserved.

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