4.8 Article

Electrochemical properties of LiNi1/3Co1/3Mn1/3O2 cathode material modified by coating with Al2O3 nanoparticles

期刊

JOURNAL OF POWER SOURCES
卷 269, 期 -, 页码 236-243

出版社

ELSEVIER
DOI: 10.1016/j.jpowsour.2014.06.101

关键词

Lithium ion batteries; LiNi1/3Co1/3Mn1/3O2; Al2O3 coating; Nano particle; Mechano-chemical bonding technology; Crack

资金

  1. Research & Development Initiative for Scientific Innovation of New Generation Batteries (RISING) project of the New Energy and Industrial Technology Development Organization (NEDO)

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LiNi1/3Co1/3Mn1/3O2 particles were coated with Al2O3 nanoparticles by means of a mechanochemical bonding process; SEM confirmed that the Al2O3 particles were uniformly coated over the surface of the LiNi1/3Co1/3Mn1/3O2 powder. During subsequent electrochemical testing using pouch cells, uncoated LiNi1/3Co1/3Mn1/3O2 exhibited a gradual capacity fading and an increase in area specific impedance (ASI) at a 50% state of charge. Under the same conditions, the increase in ASI of the Al2O3 modified samples was significantly suppressed, although the initial performance (charge/discharge capacity and ASI) slightly deteriorated. The Al2O3 coating was also effective in improving the cyclability of LiNi1/3Co1/3Mn1/3O2 at elevated temperatures by reducing the extent of cracking. (C) 2014 Elsevier B.V. All rights reserved.

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